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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 862-867 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The temporal behavior of the cathode sheath in 30 kHz 0.4–1 Torr H2 discharges has been investigated by optical emission spectroscopy. Analysis of the Stark splitting of plasma-induced H Balmer delta emission was used to measure the electric field with spatial and temporal resolution in the instantaneous cathode sheath. The location of the plasma/sheath boundary was determined from the position of the maximum of the H2 d 3Πu→a 3Σg+ (0,0) Q1 emission at 622.5 nm. Both methods showed that the sheath width increases as the cathode voltage becomes more negative, whereas the width remains constant as the applied voltage drops off. Analysis of the electric-field profile provided information on the time evolution of the ion density close to the electrode during the cathode half-cycle, in agreement with recent numerical calculations. At the beginning of the anodic half-cycle an intense flash of plasma-induced emission was observed, localized within 3 mm from the electrode.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 3384-3393 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: For applications in ultralarge scale integration, low pressure, high density plasmas are being developed for etching and deposition of thin films. To control critical parameters such as the flux and energy distribution of ions impacting surfaces, it is necessary to understand how these parameters are influenced by physical and electromagnetic design. In this work, we extend previous measurements of ion velocity distributions in Ar/He electron cyclotron resonance plasmas to Cl2/He plasmas. Using Doppler-shifted laser-induced fluorescence spectroscopy, we measure metastable Cl ion velocity distributions parallel and perpendicular to the magnetic field as a function of magnetic field amplitude, pressure, and microwave power. We also examine the effects of the wafer platen on the distribution functions by repeating the measurements after removing the platen. Surprisingly, little qualitative difference is seen when chlorine and argon discharges are compared; this is most likely a result of the low pressures employed ((approximately-less-than)0.15 Pa). As in Ar, we find nearly isotropic ion velocity distributions when the source is operated as a magnetic mirror. Downstream, we consistently observe bimodal ion velocity distributions: the fast component, created in the source, appears to follow magnetic flux lines into the reactor; the slow component, created mostly where the plasma expands from the source into the reaction chamber, is more isotropic. Despite the localized input of energy by cyclotron resonance heating, the spread in ion velocities is largely determined by distributed ionization and spatial variations in the plasma potential.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 7188-7194 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Unprecedented demands for uniformity, throughput, anisotropy, and damage control in submicron pattern transfer are spurring development of new, low pressure, high charge density plasma reactors. Wafer biasing, independent of plasma production in these new systems is intended to provide improved ion flux and energy control so that selectivity can be optimized and damage can be minimized. However, as we show here, an inherent property of such discharges is the generation of significant densities of excited, metastable ionic states that can bombard workpiece surfaces with higher translational and internal energy. Absolute metastable ion densities are measured using the technique of self-absorption, while the corresponding velocity distributions and density scaling with pressure and electron density are measured using laser-induced fluorescence. For a low pressure, helicon-wave excited plasma, the metastable ion flux is at least 24% of the total ion flux to device surfaces. Because the metastable ion density scales roughly as the reciprocal of the pressure and as the square of the electron density, the metastable flux is largest in low pressure, high charge density plasmas. This metastable ion energy flux effectively limits ion energy and flux control in these plasma reactors, but the consequences for etching and deposition of thin films depend on the material system and remain an open question.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 3648-3648 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 2552-2569 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electron cyclotron resonance (ECR) plasma reactors are being developed for etching and deposition of thin films during integrated circuit fabrication. To control critical parameters such as the flux and energy distribution of ions impacting surfaces, it is necessary to understand how these parameters are influenced by physical construction, electromagnetic design, and chemical kinetics. In this work, we report detailed measurements of ion velocity distributions in both the source and reactor regions of an ECR system using mixtures of Ar and He. Using Doppler-shifted laser-induced fluorescence spectroscopy, we measure metastable Ar-ion velocity distributions parallel and perpendicular to the magnetic field direction as a function of magnetic field amplitude, pressure, rf bias voltage, and microwave power. The measurements, in turn, are used to estimate the magnitude of electrostatic potentials and fields parallel and perpendicular to the magnetic field. Indicative of ion trapping, we find nearly isotropic ion velocity distributions when the source is operated as a magnetic mirror and the He partial pressure is low; higher He pressures tend to cool the parallel velocity distribution. Downstream, we consistently observe bimodal ion velocity distributions: the fast component, created in the source, follows magnetic flux lines into the reactor; the slow component, created mostly where the plasma expands from the source into the reaction chamber, is more isotropic. The relative amplitudes of these two components, the average ion energy, and the ion energy distribution are easily controlled by changing pressure and magnetic field.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Plasmas 5 (1998), S. 572-579 
    ISSN: 1089-7674
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The propagation of helicon waves and the plasma density has been measured in a cylindrical, magnetized plasma for a range of magnetic fields and input power levels. A transition in the coupling mechanism from electrostatic (E mode) to inductive (H mode) coupling is evidenced by a sharp change in the plasma density coinciding with a change in the wave fields from a linearly polarized standing wave, with highest amplitude close to the antenna to a right-hand elliptically polarized traveling wave with a phase velocity of about 6×106 m/s extending into the downstream region. An explanation of the transition to the H mode is put forward in terms of the conductivity across the magnetic field and an associated skin depth for power deposition. The polarization of the wave fields in the H mode is interpreted in terms of the interference between m=+1 and −1 modes (where m is the azimuthal mode number). © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: High-density plasmas are being used in the manufacture of electronic devices and systems because they provide high throughput at low pressure and low ion energy. Low pressure is desirable for maximizing process uniformity over large substrates while low ion energy is desirable for minimizing process-induced damage. However, the optimal design for a high density plasma reactor is unclear and the technology has largely developed empirically: many alternatives for magnetic and geometric design are offered for the same processing applications. In this talk we discuss diagnostic measurements of high density plasma reactors and how they can be used in developing improved reactor designs and in providing insight into materials processing. Laser-induced fluorescence measurements of metastable ion velocity distributions are made in both Ar and Cl2 electron cyclotron resonance and helicon plasmas. The effects of magnetic field configuration, power, and pressure on the energy and angular distributions of the ions will be described along with electron density measurements made by microwave interferometry. Where appropriate, comparisons will be made with the recent theoretical results of Graves and Porteous [D. B. Graves and R. K. Porteous, American Vacuum Society National Symposium, Seattle, WA, November (1991)].
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 8976-8981 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Time resolved maps of the electric field magnitude in the sheath of discharges in pure H2 have been determined as a function of pressure (0.6 and 1 Torr) and excitation frequency (30 kHz, 1, and 2.78 MHz). The electric field was determined from the Stark splitting of the n=6 level of atomic hydrogen using 2+1 photon laser-induced fluorescence of ground state hydrogen atoms. The sheath electric field oscillations throughout the rf cycle were observed for different values of the rf driving frequency, corresponding to different regimes. We observe a "low'' frequency regime at 30 kHz, a "high'' frequency regime at 2.78 MHz, and an intermediate regime at 1 MHz, depending on whether the ion density profile is modulated during the rf cycle. This is the first observation of an intermediate regime where the ion transit time across the sheath is comparable to the rf period. Fluid model simulations were carried out and are in good agreement with our experimental observations. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 58 (1991), S. 458-460 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Ion and neutral temperatures are measured by high-resolution laser-induced fluorescence spectroscopy both in the source and downstream of an electron cyclotron resonance discharge through mixtures of Ar, Ar/Ne, and Ar/He. Contrary to previous reports, both ions and neutrals are found to be cold. In the source, ion temperatures perpendicular to the magnetic field are ≤0.5 eV; downstream they are ∼0.25 eV. Neutral temperatures in the source and downstream are 0.068 and 0.030 eV, respectively.
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  • 10
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electron cyclotron resonance plasma sources are gaining widespread use in plasma processing because they offer high ion flux with controllable energy and thereby high etching and deposition rates with minimal damage. However, it is unclear how ion energy distributions evolve from source to wafer as a function of plasma parameters such as pressure, microwave power, and magnetic field strength. Therefore, we used Doppler broadened and shifted laser-induced fluorescent line profiles to measure Ar+ metastable ion velocity distributions downstream from a divergent magnetic field electron cyclotron resonance source. Spatially resolved distributions, measured at positions above and across a wafer platen, differ markedly from shifted Maxwell–Boltzmann functions. Ions are accelerated along the magnetic field direction by a weak (∼0.5 V/cm), ambipolar electrostatic field. The ion energy component perpendicular to the electric field corresponds to a temperature of only 0.46±0.10 eV. On the edges of the platen, the magnetic and electrostatic fields diverge causing angled acceleration of ions.
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