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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Plasma chemistry and plasma processing 5 (1985), S. 67-79 
    ISSN: 1572-8986
    Keywords: Oxygen discharge ; degree of dissociation ; ozone ; Wrede-Harteck method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract The degree of dissociation of oxygen has been measured in the positive column plasma of a glow discharge by two different methods (the ozone method and the Wrede-Harteck method). The results of both methods are in a good agreement. The pressure was varied from 66 to 266 Pa, the discharge current from 4 to 100 mA, and the discharge tube was of 2.0 cm inside diameter. As expected, the degree of dissociation increases with increasing discharge current and decreases with increasing pressure. Calculations of the degree of dissociation show that the main loss process of the oxygen atoms is caused by the recombination on the wall of the discharge tube for pressures up to several 100 Pa. We found that the value of the recombination coefficient for the glass wall of the discharge tube (γ≈4.6·10−4) is about a factor 2 larger than that for a tube outside of the discharge (γ≈2.2·10−4). Ozone processes, including metastable oxygen molecules, have increasing influence on the balance of the oxygen atoms as the pressure increases.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Plasma chemistry and plasma processing 8 (1988), S. 425-444 
    ISSN: 1572-8986
    Keywords: rf planar discharges ; Langmuir probes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Langmuir probe studies have been performed on rf (27.1 MHz) discharges in O2 under planar reactor conditions to determine the axial variation of the plasma parameters (positive ion density, electron temperature, and dc space potential) as a function of pressure (20–220 Pa) and power (10–150 W) or current (0.1–2 A). By monitoring the second derivative of the I–V probe characteristics, the suppression of the rf component in the probe circuit can be optimized. Referring to this problem, numerical studies provide relations for the determination of the residual rf component as well as of the dc component of the plasma potential at incomplete rf compensation. The positive ion density is obtained from the ion saturation currents. Here the effect of collisions between ions and neutral particles within the probe sheath (for p〉 100 Pa) is considered. The electron energy distribution function is found to be of the Maxwellian type for all discharge conditions investigated here. If the pressure and the power exceed critical values, the axial charge carrier distribution is characterized by a valley formation in the bulk plasma center. This fact demonstrates that secondary electron emission due to ion impact on the electrode surfaces and following ionization by these electrons near the sheaths in front of the electrodes are significant processes for sustaining the discharge. At low pressures (p≤60 Pa) the dc plasma potential was found to be identical with the half-peak maintaining voltage of the discharge, in agreement with the model idea of a symmetric rf planar discharge where the rf voltage drop across the bulk plasma can be neglected. For growing pressure, however, the plasma system moves gradually toward a situation where the V-I characteristics of the discharge are significantly controlled by processes in the bulk plasma. This transition depends on the current density.
    Type of Medium: Electronic Resource
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