ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 59 (1996), S. 609-617 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The chemical grafting of acrylamide-methacrylic acid (AAM-MAA) mixture onto poly(ethylene terephthalate) (PET) fibers using azobisisobutyronitrile as a chemical initiator was investigated. The use of MAA as a comonomer increased the amount of AAM introduced to the PET fiber up to 33.0%, while the grafting of AAM onto fibers alone gave low graft yields. This synergistic effect was found to be at its highest when an AAM-MMA mixture having 30 wt % AAM was used. The grafting increased dyeability with both acidic and basic dyes, and increased diameter and decreased the density of the fibers. The thermogravimtric analysis results revealed that the decomposition temperature of the fibers decreased with grafting. The electron micrographs showed that grafting changed the surface morphology of the fiber and a shell-like heterogeneous structure occurred at the surface at high graft yields. © 1996 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 59 (1996), S. 1191-1194 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The grafting of acrylamide onto poly(ethylene terephthalate) fibers using hydrogen peroxide as the redox initiator was investigated. Benzyl alcohol was found to be the favorite medium for this grafting. Maximum graft yield (7.6%) was reached at 95°C; the graft yield decreased at higher temperatures, and finally grafting was inhibited at 120°C. The effect of monomer and initiator concentration on grafting was also studied. © 1996 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 39 (1996), S. 153-159 
    ISSN: 0959-8103
    Keywords: conductive polymers ; polyaniline ; oxalic acid ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Conductive polyaniline was synthesized in aqueous 1.0M oxalic acid containing 0.1 M aniline by electrochemical and chemical oxidation and characterized by conductivity, solubility, ultraviolet and infrared spectroscopy, and cyclic voltammetry. The solubility experiments showed that the solubility of oxalic acid-doped polyaniline in dimethylsulfoxide and dimethylformaide increased to a certain extent. The soluble part of the polyaniline was free from impurities such as quinones. Cyclic voltammetric studies in oxalic acid medium revealed that aniline exhibited a similar behaviour to that in H2SO4 and the polymerization rate was much slower than that in H2SO4.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 44 (1992), S. 1737-1742 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The graft copolymerization of methacrylic acid onto poly(ethylene terephthalate) fibers, by the aid of benzoyl peroxide, have been investigated. The graft yield increased up to 85°C, and then decreased with the further increase in temperature. The maximum graft yield was obtained at benzoyl peroxide concentration of 4.0 × 10-3 mol/L. The increase in the concentration of monomer was found to increase the graft yield. The change in the graft yield was followed by the experiments carried out using different water/solvent mixtures. Also, the change in the properties of polye (thylene terephthalate) fibers grafted with methacrylic acid such as moisture regain, density, and diameter were investigated.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 50 (1993), S. 1123-1129 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In this study, the grafting of methyl methacrylate onto poly(ethylene terephthalate) fibers using azobisisobutyronitrile is reported. An increase in temperature and monomer concentration were found to increase the graft yield. The graft yield increased up to an initiator concentration of 0.90 × 10-2 mol/L and decreased at higher initiator concentrations. The fiber densities decreased, and fiber diameters and intrinsic viscosities increased with increasing graft yield. Moisture regain values showed a slight increase with the grafting. Fiber orientation decreased the graft yield to an important extent. The overall activation energy for grafting was calculated to be 11.9 kcal/mol. © 1993 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 50 (1993), S. 1909-1916 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The grafting of acrylic acid onto poly(ethylene terephthalate) fibers subjected to a noswelling treatment using benzoyl peroxide was investigated. The temperature was found to increase the graft yield. The grafting yield increased up to a benzoyl peroxide concentration of 4.0 × 10-3 M and slightly decreased at higher initiator concentrations. The effects of solvents such as dimethylformamide, dimethylsulfoxide, pyridine, and some alcohols upon the grafting were examined by carrying out the graft copolymerization at various water/solvent ratios. Pyridine was found to inhibit the grafting totally. The properties of the grafted fibers such as density, diameter, dyeability, and moisture regain were also investigated. It was concluded due to the observations made in these properties that the grafting took place mainly in the subsurface regions of the fibers and there occurred a diffusion barrier after the grafting value of 8-9%. The overall activation energy for grafting was calculated to be 9.9 kcal/mol. © 1993 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 59 (1996), S. 1347-1354 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Electrochemical polymerization of aniline, on a Pt foil electrode coated with poly(methyl methacrylate) (PMMA), produces a homogeneous, free-standing, flexible, and conductive polymer film. The conductivity of the films depends on the aniline content and reaches 0.1-0.2 S/cm for films having aniline content of 15% or more. The optimum thickness of precoated PMMA to obtain durable conducting films was found to be in the range of 10-15 μm. Cyclic voltammetric investigation revealed that aniline exhibits a similar electrochemical behavior on a PMMA coated platinum electrode similar to a bare Pt surface. The film gives a fast and reproducible response against ammonia gas within a concentration range of 1.0-0.01%. Scanning electron micrographs indicate that the films have a rough structure consisting of globular regions. © 1996 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2007-09-01
    Print ISSN: 0379-6779
    Electronic ISSN: 1879-3290
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Elsevier
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Publication Date: 2009-07-01
    Print ISSN: 0379-6779
    Electronic ISSN: 1879-3290
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Published by Elsevier
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...