ISSN:
0049-8246
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Physics
Notes:
The geometrical properties of the x-ray fluorescence (XRF) intensity related to the α-parameterization were confirmed experimentally. A special sample stage was built to allow the rotation of the sample with the propagation plane (the plane defined by the incident and take-off beam directions) and was coupled to an energy-dispersive spectrometer. The device and the way in which it was carefully aligned with the collimated x-ray beams are described. The fluorescence spectra of three NBS standard samples were measured for 16 different positions of the α angle. The incident and take-off angles were both 45° for sample rotations between α = 0 and the maximum angle of 86°. XRF intensities from non-enhanced lines do not show any dependence on α as predicted by theory. Enhanced lines, on the contrary, decrease in intensity when α increases, allowing the isolation of the primary emission by extrapolation to the limiting case α = π/2.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/xrs.1300200403
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