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  • 1
    ISSN: 1572-879X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Four catalysts, H2PtCl6-5SnCl2/γ-Al2O3 (cat-1), { H2PtCl6-5SnCl2 + xLaCl3 } / γ-Al2O3 (cat-2), (Me4N)[Pt(SnCl3)5]/ γ-Al2O3 (cat-3), and {(Me4N)[Pt(SnCl3)5] + xLaCl3} / γ-Al2O3 (cat-4) were prepared and their catalytic activities and stabilities in dehydrogenation of propane were investigated. It has been shown that the stabilities of the Pt-Sn bimetallic catalysts were improved by introducing lanthanum into the catalysts either by the conventional impregnation method with Pt- and Sn-containing salts or by using precursors derived from Pt-Sn bimetallic clusters. Results from XPS analysis indicated that addition of lanthanum could inhibit the reduction of tin in the catalysts, especially in cat-2. The distribution of pore capacity in a used cat-2 was mainly in the large and medium size range, but in a used cat-1 the distribution was mainly in the small to medium size range. Thermal gravimetric analysis (TGA) showed that weight loss in the used cat-1 was much more than that in the used cat-2. The results suggested that introducing lanthanum into the Pt-Sn bimetallic catalysts could effectively prevent them from coking.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2012-04-09
    Description: N-type microcrystalline silicon oxide thin films (n-μc-SiOx:H) have been deposited by VHF-PECVD (40 MHz) with reactant gas mixtures of CO2/SiH4 and H2. N-μc-SiOx thin films exhibiting low refractive index value (n600 nm~2), and medium/high conductivity (≧10-9 S/cm) are suitable to be used as an “n-type reflector” in micromorph tandem solar cells. Transmission electron microscopy (TEM) results show that microstructures of n-μc-SiOx:H thin films contain nanocrystalline Si particles, which are randomly embedded in the a-SiOx matrix. This specific microstructure provides n-μc-SiOx:H thin films excellent optoelectronic properties; therefore, n-μc-SiOx:H thin films are appropriate candidates for “n-type reflector” structures in Si tandem solar cells.
    Print ISSN: 1110-662X
    Electronic ISSN: 1687-529X
    Topics: Electrical Engineering, Measurement and Control Technology , Energy, Environment Protection, Nuclear Power Engineering
    Published by Hindawi
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