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  • 1
    Electronic Resource
    Electronic Resource
    Epoxy-amine multimethacrylic prepolymers, kinetic and structural studies (1995)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 175-184 
    Details
    ISSN: 0887-624X
    Keywords: epoxy-amine ; methacrylate ; acrylate ; prepolymers ; synthesis ; kinetics ; Michael reaction ; catalyst ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Epoxy-amine methacrylated prepolymers are prepared in a 1-step synthesis by the reaction of Bisphenol A diglycidyl ether, glycidyl methacrylate, and different diamines. The adaptation of these reactions to production processes with a reduced reaction time requires a kinetic control and the use of efficient catalysts. The comparative kinetic treatment of the epoxy-amine reaction in the frame of Horie's and Rozenberg's kinetic schemes have been made. Cases where an efficient acid catalyst is used are also examined. Structural studies of these reactions established the occurrence of a Michael amine/double bond addition, when some amines are used. © 1995 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1995.080330120
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Morphology control at phase separation of curing multicomponent thermosets (1996)
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 7 (1996), S. 356-364 
    Details
    ISSN: 1042-7147
    Keywords: heterophase polymers ; cure reaction-induced phase separation ; morphology ; criterion of equilibrium ; toughened epoxies ; epoxy-rubber polymers ; adhesion interaction between phases ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The process of phase separation in the course of the thermoset curing reaction is considered. Clarification of the role of kinetic factors in such processes is the focus of the article, and the need in a kinetic theory for cure reaction-induced phase separation (CRIPS) is substantiated. An adequate nonequilibrium approach proposed previously is given further development. A new CRIPS model with equilibrium boundary conditions is introduced.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 3
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    Unusual case of network polymer formation in anionic polymerization of monofunctional vinyl monomer (2006)
    Springer
    Details
    Publication Date: 2006-07-27
    Print ISSN: 0170-0839
    Electronic ISSN: 1436-2449
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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