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  • 1
    Publication Date: 2023-01-13
    Description: In order to investigate the deformation within the upper plate of the Calabrian subduction zone, we have mapped and modeled a sequence of Late Quaternary paleoshorelines tectonically deformed by the Capo D'Orlando normal fault, NE Sicily, which forms part of the actively deforming Calabrian Arc. In addition to the 1908 Messina Strait earthquake (Mw 7.1), this region has experienced damaging earthquakes, possibly on the Capo D'Orlando Fault; however, it is not considered by some to be a potential seismogenic source. Uplifted Quaternary paleoshorelines are preserved on the hangingwall of the Capo D'Orlando Fault, indicating that hangingwall subsidence is counteracted by regional uplift, likely because of deformation associated with subduction/collision. We attempt to constrain the relationship between regional uplift, crustal extensional processes, and historical seismicity, and we quantify both the normal and regional deformation signals. We report uplift variations along the strike of the fault and use a synchronous correlation technique to assign ages to paleoshorelines, facilitating calculation of uplift rates and the fault throw rate. Uplift rates in the hangingwall increase from 0.4 mm/year in the center of the fault to 0.89 mm/year beyond its SW fault tip, suggesting 0.5 mm/year of fault-related subsidence, which implies a throw rate of 0.63 ± 0.02 mm/year, and significant seismic hazard. Overall, we emphasize that upper plate extension and related vertical motions complicate the process of deriving information on the subduction/collision process, such as coupling and slip distribution on the subduction interface, parameters that are commonly inferred for other subduction zones without considering upper plate deformation.
    Description: Published
    Description: 1231–1255
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: normal-faulting; palaeoshorelines; Quaternary; sea-level changes; synchronous correlation method; uplift-rate
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2023-01-13
    Description: The Cotentin Peninsula (Normandy, France) displays sequences of marine terraces and rasas, the latter being wide Late Cenozoic coastal erosion surfaces, that are typical of Western European coasts in Portugal, Spain, France and southern England. Remote sensing imagery and field mapping enabled reappraisal of the Cotentin coastal sequences. From bottom to top, the N Cotentin sequence includes four previously recognized Pleistocene marine terraces (T1 to T4) at elevations 〈 40 m as well as four higher and older rasas (R1 to R4) reaching 200 ± 5 m in elevation. Low-standing marine terraces are not observed in the central part of the Peninsula and a limited number of terraces are described to the south. The high-standing rasas are widespread all over the peninsula. Such strandline distributions reveal major changes during the Late Cenozoic. Progressive uplift of an irregular sea-floor led to subaerial exposure of bathymetric highs that were carved into rocky platforms, rasas and marine terraces. Eventually, five main islands coalesced and connected to the mainland to the south to form the Cotentin Peninsula. On the basis of previous dating of the last interglacial maximum terrace (i.e. Marine Isotopic Stage, MIS 5e), sequential morphostratigraphy and modelling, we have reappraised uplift rates and derived: (i) mean Upper Pleistocene (i.e. since MIS 5e ~ 122 +/− 6 ka, i.e. kilo annum) apparent uplift rates of 0.04 ± 0.01 mm/yr, (ii) mean Middle Pleistocene eustasy-corrected uplift rates of 0.09 ± 0.03 mm/yr, and (iii) low mean Pleistocene uplift rates of 0.01 mm/yr. Extrapolations of these slow rates combined with geological evidence implies that the formation of the sequences from the Cotentin Peninsula occurred between 3 Ma (Pliocene) and 15 Ma (Miocene), which cannot be narrowed down further without additional research. Along the coasts of Western Europe, sequences of marine terraces and rasas are widespread (169 preserve the MIS 5e benchmark). In Spain, Portugal, S England and other parts of western France, the sequences morphostratigraphy is very similar to that of Cotentin. The onset of such Western European sequences occurred during the Miocene (e.g. Spain) or Pliocene (e.g. Portugal). We interpret this Neogene-Quaternary coastal uplift as a symptom of the increasing lithospheric compression that accompanies Cenozoic orogenies.
    Description: Published
    Description: 338-356
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Cotentin and Western Europe; Marine terrace; Neogene and Quaternary coastal uplift; Rasa
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of medicinal chemistry 17 (1974), S. 116-120 
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 2998-3003 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The photoluminescence (PL) of amorphous hydrogenated carbon (a-C:H) has been investigated as a function of optical gap and excitation energy. The PL spectra exhibit a red shift when the excitation energy falls below the optical gap. The bandwidth of the PL spectra increases with the excitation energy but depends very weakly on the gap. The results are discussed in terms of the electronic structure of a-C:H and the configuration of sp2 sites. It is proposed that PL arises by the geminate radiative recombination of the electron–hole pairs confined to the π states of the sp2 bonded clusters. The quantum efficiency is found not to decrease for excitation above the gap, indicating that the electron–hole pair remain bound, and suggesting that any mobility edges lie beyond the optical band edges. The PL efficiency is found to increase roughly exponentially with optical gap, displaying two regimes. At higher gap the efficiency depends just on the gap, while at lower gap the dependence may depend on the capture radius of nonradiative recombination centers. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 4388-4396 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The process of bias enhanced nucleation of microwave chemical vapor deposited diamond on silicon has been extensively characterized using plasma diagnostics, scanning and transmission electron microscopy (TEM), Raman spectroscopy, and x-ray diffraction. The nucleation kinetics were measured as a function of bias voltage, methane partial pressure, and substrate temperature. The nucleation is found to be transient in character, with a delay time followed by an exponential increase in nucleation density with time, and finally a saturation. The ion flux and ion energy distribution was measured by a retarding field probe. The nucleation density was found to reach a maximum at a bias at which the ion energy distribution has a maximum of 80 eV, independent of the substrate temperature. This is taken as strong evidence that nucleation enhancement involves ion subplantation. The Raman spectra and x-ray diffraction suggests that the films during nucleation consist primarily of sp2 bonded noncrystalline carbon. The presence of the (0002) interlayer graphitic peak suggests that the carbon is primarily graphitic. The diamond nuclei form in this matrix. TEM shows mainly amorphous hillocks being formed on the substrates by bias enhanced nucleation. Diffraction patterns and high resolution TEM reveal the presence of β-SiC and also a small number of diamond particles. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present the effects of antiferromagnetic (AF) order of the Cr spacers in Fe/Cr(001) superlattices on the interlayer coupling of the Fe layers. AF order of the Cr spacers is suppressed for layer thicknesses less than 42 A(ring). For (approximately-greater-than)42 A(ring) of Cr, the Néel temperature (TN) increases rapidly and asymptotically approaches the bulk value for thick Cr spacers as characterized by a transition-temperature shift exponent λ=1.4±0.3. Neutron diffraction confirms both the AF order of the Cr layers in superlattices with 62, 100, and 200 A(ring) thick Cr layers, and the existence of the incommensurate, transverse spin-density-wave magnetic structure whose nesting wave vector is equal to that of bulk Cr. The AF ordering of the Cr results in anomalies in a variety of magnetic properties, including the interlayer coupling, remanent magnetization, coercivity, and magnetoresistance. Most strikingly, the 90° or "biquadratic'' coupling of the Fe layers observed for T(approximately-greater-than)TN is suppressed below TN as confirmed by polarized neutron reflectivity. This behavior can be understood in terms of the combination of finite-size and spin frustration effects at rough Fe/Cr interfaces. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 8318-8322 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We performed inelastic neutron scattering measurements on nanophase Fe powders prepared by high-energy ball milling. Neutron energy loss spectra were measured for two states of the material: (1) as milled, when the material had a characteristic nanocrystallite size of 12 nm; and (2) annealed, when the material had a characteristic crystallite size of 28 nm. The longitudinal peak in the phonon density of states (DOS) of the nanophase Fe was broadened, compared to that of the annealed material. We attribute this broadening to short phonon lifetimes in nanocrystals. The nanophase material also showed an enhanced density of states at low energies below 15 meV, which may indicate the presence of intercrystallite vibrations. These differences in phonon DOS should have only a small effect on the difference in vibrational entropy of nanocrystalline and larger-grained Fe. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 245-250 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effect of water vapor on the mechanisms of nucleation and growth of metallo-organic chemical vapor deposited copper films from copper (II) hexafluoroacetylacetonate [Cu(hfa)2] on a polyimide substrate has been investigated. Minimal copper deposition was observed on the polyimide substrate in the absence of water vapor. When water vapor was introduced into the system, blanket copper deposition was observed on the whole polyimide surface. The initial nucleation and growth of copper film on polyimide is initiated by the reaction between the vapor phase precursor and water vapor not the surface chemistry reaction between the vapor phase precursor and the substrate. Copper film growth on the polyimide substrate can thus be attributed to an initial oxidation of the organic ligand by water vapor followed by reduction of the resulting copper oxide by hydrogen. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 9250-9257 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We show the alignment of defect dipoles along the direction of the spontaneous polarization in polycrystalline Pb(Zr,Ti)O3 and BaTiO3 ferroelectric ceramics using electron paramagnetic resonance (EPR). The alignment is demonstrated via orientation dependent paramagnetic centers in the polycrystalline materials and computer modeling of the EPR line shapes. It is shown that defect dipoles can become aligned by oxygen vacancy motion in the octahedron about a negatively charged center for the oxygen vacancy-related dipole complexes or by defect displacement and domain realignment in the lattice for isolated defect centers. We find that the alignment is not observed in nonferroelectric materials such as SrTiO3, and is destroyed in ferroelectric materials by heating above the Curie temperature. These observations suggest an interplay between distortion in the unit cell and the ability to align defect dipoles, as is the case more generally for ferroelectric dipole alignment. We also directly observe aligned intrinsic Ti and Pb ion displacements in the ferroelectric Pb(Zr,Ti)O3 perovskite unit cell. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 3975-3980 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Band structure calculations and electron paramagnetic resonance measurements are used to show that Pb states determine many of the electronic properties of Pb(Zr,Ti)O3 ferroelectric materials. The valence-band edge consists of hybridized Pb s and O p states at all compositions. The conduction-band minimum changes from a Ti d-like Γ25' state to a Pb p-like X1 state with increasing Zr content. The Pb p character accounts for the relatively small 0.2 eV increase in band gap in the Pb(Ti,Zr)O3 alloys with Zr content compared to the large 2 eV increase in band gap in Ba(Ti,Zr)O3 alloys. The paramagnetic Pb3+ hole center is found to become deeper and acquire some p character as the Zr content is raised. This is attributed to the change in conduction-band character combined with a local off-center displacement of the Pb3+ ion. © 1995 American Institute of Physics.
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