ISSN:
0009-2940
Keywords:
Pentaphosphorus ligands
;
Pentaarsenic ligands
;
Stacking reaction
;
Tripledeckers, neutral 30 valence-electron
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Neutral 30 Valence-Electron Tripledecker Complexes with cyclo-E5 Middle Deck (E = P, As)[1]In a stacking reaction of [(η5-E5)M(η5-C5Me5)] (3: E = P, As; M = Fe, Ru) with [M′(CO)3(NCMe)3] (4: M′ = Cr, Mo, W) at room temperature the neutral 30 valence-electron tripledecker complexes [(η5-C5Me5)M(μ-η5:5-E5) M′(CO)3] (5) are formed. Complexes 5b (M = Fe, E = P, M′ = Mo) and 5c, d (M = Fe, E = As, M′ = Cr, Mo) have been characterized by X-ray structure analyses.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250506
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