Publication Date:
2012-06-16
Description:
The catalytic activity of two CNC palladium pincer complexes is evaluated in two fundamental C C bond-forming reactions: Mizoroki Heck and Sonogashira cross-couplings. After several optimization attempts and a brief comparison with a PCN pincer catalyst, a number of arylated alkenes and diarylethynes are synthesized by procedures based on the catalytic use of the above mentioned CNC Pd pincers in H 2 O and DMF.
Print ISSN:
0018-019X
Electronic ISSN:
1522-2675
Topics:
Chemistry and Pharmacology
Permalink