ISSN:
1077-3118
Source:
AIP Digital Archive
Topics:
Physics
Notes:
Electron paramagnetic resonance (EPR) has been used to investigate an acceptor in as-grown single crystals of ZnGeP2. The spectra are characterized by equally spaced triplets with 1:2:1 intensity ratios representing hyperfine interactions (varying from 35 to 55 G in magnitude) with two equivalent phosphorous nuclei. Their angular dependence shows that there are four crystallographically equivalent orientations of the defect. The principal values of the g matrix are 2.002, 2.021, and 2.074 and the corresponding principal axes, at one of the four sites, are the [011], [1¯00], and [01¯1] directions, respectively. Two possible models are suggested for this acceptor: Either a zinc vacancy (VZn) or a zinc ion on a germanium site (ZnGe). It also is suggested that the acceptor responsible for the EPR signal is the same acceptor, namely AL1, that gives rise to a dominant near-infrared absorption band.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.111855
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