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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 3 (1992), S. 33-42 
    ISSN: 1573-4838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Technology
    Notes: Abstract Plasma spraying is a commonly used technique to apply thin calcium phosphate ceramic coatings. Special consideration is given to retaining the original structure of CPC particles. However, changes are possible. Thus this study focused on plasma spraying induced changes in material characteristics of commercial coatings and their influence onin vitro dissolution. All analysed coatings were found to undergo significant plasma spraying induced changes in phase composition, crystal structure, and specific surface area. The phase transformations depended on the starting particle characteristics. Specifically, β-TCP transformed to α-TCP. HA was dehydroxylated and transformed to oxyhydroxyapatite (OHA), and partly decomposed to α-TCP and tetra calcium phosphate. These transformations lead to a considerable increase ofin vitro dissolution rates at physiological pH.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 28 (1994), S. 1303-1309 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: In vitro reaction kinetics of surface transformations of porous and dense bioactive ceramics were studied after immersion in simulated physiologic solution (SPS). Porous ceramics with identical macroporosity were commercially obtained: calcium carbonate marine coral (I-CC), coralline HA (I-HA), and a product, labeled as β-tricalcium phosphate, which was partially transformed into β-calcium pyrophosphate (I-β-CP). Previously studied dense ceramics were used for comparison: Ca-deficient HA (CDHA), stoichiometric HA, both well and not well crystallized (wc and nwc s-HA), β-and α-tricalcium phosphate (β- and α-TCP). The induction time to precipitation increased as follows: CDHA, nec HA 〈 wc HA, I-HA 〈 β-TCP, I-CC 〈 I-β-CP. The reaction kinetics of ceramics with identical macroporosity varied substantially depending on composition, crystal structure, and ultrastructure. One of the porous ceramics, I-β-CP, showed an inhibiting effect on precipitation reactions. © 1994 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 27 (1993), S. 1461-1461 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 27 (1993), S. 35-45 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The formation of a biologically equivalent carbonatecontaining apatite on the surface of synthetic calcium phosphate ceramics (CPC) may be an important step leading to bonding with bone. Reactions of several single phases CPCs upon immersion into a simulated physiologic solution (SPS) with an electrolyte composition of human plasma were determined. The CPCs covered a wide range of solution stabilities from low-soluble hydroxyapatites (HA) to metastable tricalcium phosphates (TCP) and tetracalcium phosphate (TTCP). Changes in chemical composition of SPS and infrared spectral features after CPC immersion were analyzed. New phase formation was observed on all the CPCs. However, kinetics, compositions, and structures of the new phases were significantly different. The studied CPCs can be characterized by the time to new phase formation in vitro; the minimum time for measurable precipitate formation was found to increase in the order: not-well-crystallized HAs 〈 well-crystallized HAs 〈 α-TCP, TTCP 〈 β-TCP. Among the CPCs only not-well-crystallized HAs led to immediate new phase formation. The metastable CPCs, β-TCP, α-TCP, and TTCP required an induction time during which dissolution occurred. β-TCP showed the longest induction time and the lowest lattice ion uptake rate of all the CPCs tested. Only the not-well-crystallized HAs elicited immediate formation of carbonated HA. The well-crystallized HAs and β-TCP did not elicit carbonated apatite formation within the time frame of the experiment. Instead, intermediate phases were formed. On α-TCP amorphous calcium phosphate (ACP) with a relatively low carbonate content was formed. TTCP was found to transform extensively to poorly crystallized carbonated apatite after 2 days of immersion. © 1993 John Wiley & Sons, Inc.
    Additional Material: 12 Ill.
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