ISSN:
0947-6539
Keywords:
alkenes
;
allylsilanes
;
C-C coupling
;
cross-metathesis
;
jasmonates
;
molybdenum
;
ruthenium
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The applicability of olefin cross-metathesis for the synthesis of different unsymmetrically substituted functionalized olefins is described. The coupling of different functionalized olefins in the presence of Grubbs' ruthenium catalyst or Schrock's molybdenum catalyst afforded the crossed products in good yields and with very high selectivities. Derivatives of jasmonic acid and functionalized allylsilanes were prepared by this catalytic method for carbon-carbon double bond formation.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/chem.19970030316
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