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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 9 (1969), S. 360-364 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Equations have been derived to convert Brabender flow curves to Instron flow curves for practical application purposes. The technique involved is simple and has been described and discussed in detail. Nine pairs of Brabender and Instron flow curves of three different high polymers, each at three operating temperatures, have been found to fit each other quite well. The converted Brabender flow curves overlap a part of the Instron curves and extend the shear range toward the Newtonian flow region. An important consequence of this work is that the Brabender Plastograph can now be regarded as a formal viscometer while still functioning as a miniature of the Banbury mixers used in industry. More work is being done to take advantage of this consequence.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Branching analyses in styrene-butadiene rubbers and polybutadiene rubbers have revealed large differences in branching between rubbers polymerized in different ways. The functionalities of several star-branched solution-polymerized styrene-butadiene rubbers were calculated and compared to their expected structures. Emulsion-polymerized polybutadiene rubber and a series of solution-polymerized polybutadienes made with different catalysts had different degrees of random branching, and evidence is presented indicating that the different available catalyst systems provide some latitude in making rubbers of different branching contents. Random branching analyses on a series of emulsion-polymerized styrene-butadiene rubbers revealed the dependency of branching on molecular weight and molecular weight distribution. The influence of polymerization temperature on the branching of emulsion-polymerized styrene-butadiene rubber was also studied.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 57 (1962), S. 453-469 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An investigation has been carried out to further establish the usefulness of electrical resistivity techniques for the study of polymerization kinetics, and to determine the extent of molecular weight dependence of electrical resistivity. The resistivity increment, (p - p0)/p0, which may be regarded as the fractional increase in resistivity of a system due to the presence of polymer, was found to be directly proportional to the concentration of polymer in solution. Based on the assumption that conductance in polymeric systems occurs by migration of ionic impurities, the resistivity increment was shown to be identical to the specific local viscosity. A marked dependence of (p - p0)/p0 upon molecular weight was found. The relationships observed provide expressions for determination of molecular weight from resistivity data in the systems: polystyrene-styrene, polystyrene-cyclohexane, and poly(methyl methacrylate)-benzene. Furthermore, these relationships indicate the existence of a “critical packing volume” for the polymer chains in solution. This effect permits a determination of the unperturbed end-to-end chain dimension of the polymer (polystyrene) which agrees reasonably well with the published value.
    Additional Material: 13 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Letters 1 (1963), S. 451-453 
    ISSN: 0449-2986
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The technique for determining branching in polymers by using a combination of GPC and intrinsic viscosity data has been extended beyond current methods. Equations used in these analyses are presented. The derivations are based upon the assumption that branching is present only when there is a measurable reduction in the intrinsic viscosity. Techniques for calculating the functionality of the star branch point in starbranched polymers are given. Three random-branching parameters are calculated from a knowledge of the average branching density, \documentclass{article}\pagestyle{empty}\begin{document}$ \bar \lambda $\end{document}: (a) the lowest molecular weight branched polymer that can be measured, M̄*; (b) the average molecular weight between branch points, M̄bp; (c) the weight percentage of polymer that is branched. The applicability of this technique is demonstrated by using an analysis of published data on characterized fractions of a randomly branched polystyrene.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 6 (1968), S. 243-246 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 8 (1970), S. 1306-1308 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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