ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The reaction of 2-cinnamoylcyclohexa[b]oxirane with allylamine gave cis-2(β),3,4a,5,6,7,8,8a(β)-octahydro-1-allyl-4a(β)-hydroxy-(2α)-phenylquinolin-4-one, which upon subsequent reaction with dimethyl malonate, peroxide epoxidation, and heating with hydrochloric acid gave cis-4,5,6a(β),7,8,9,10a-octa-hydro-6-allyl-20-oxo-5(α)phenyl-3-chlorofuro[3,2-d]quinoline. Heating of this intermediate in 96% sulfuric acid gavetrans-3a(a),7a(a),9,10(β),14b(α),15-hexahydro-10(α)-methyl-2-oxo-1-chlorobenzo[a]cyclo-hexa[f]furo[2,3-g]quitiolizine.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01165707
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