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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 36 (1995), S. 309-313 
    ISSN: 0959-8103
    Keywords: high impact polystyrene ; polychromatic irradiation ; viscosity ; tensile impact ; yellowing ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Different grades of impact-modified polystyrene were studied by viscometry, tensile impact test and colour change upon exposure to polychromatic irradiation at 55°C in air. The samples underwent extensive reduction in intrinsic viscosity [η] and tensile impact strength, and yellowed upon polychromatic irradiation (λ ≥ 290 nm). Chain-scission during photo-oxidative degradation was also studied under conditions where evolution of volatiles was negligible. Tristimulus values were calculated for unirradiated and irradiated samples. The rate of oxidative degradation was maximum in the sample possessing higher unsaturation content.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 59 (1996), S. 953-959 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The polybutadiene (PB) content and its microstructure in different grades of high impact polystyrene (HIPS) has been studied by various spectroscopic techniques. PB is characterized by deformation bands in FTIR spectroscopy at 994, 967, 912, and 729 cm-1. FT-Raman was used for higher constant resolution over the range of wave numbers. It provides reasonable signal to noise ratios in near IR excited Raman. Proton and 13C-NMR spectroscopy was utilized for the determination of polybutadiene content in HIPS and tacticity, and reactivity ratios. © 1996 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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