Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
116 (2002), S. 8588-8595
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The mean spherical approximation (MSA) was used to investigate the phase behavior of charged colloidal systems with and without added salt. The competition between cohesive Coulomb interactions and stabilizing entropic and hard-core interactions controls the stability of the system and under certain circumstances, a liquid–gas-type phase transition can occur. The critical parameters and phase diagrams in the MSA obtained via the internal energy path, are compared with two-component Monte Carlo simulations and other theoretical approaches. © 2002 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1469606
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