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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 360-364 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 1:1-Complexes of Mercuric Halides with MethyldiphenylstibineThe complexes [HgX2·SbCH3(C6H5)2]2 mit X=Cl (5), Br (6), J (7) precipitated on combination of equimolar amounts of the components in methanol or acetone solution. Dimeric, halogen-bridged structures for these complexes have been derived from infrared spectra (300-33/cm). The ligand methyldiphenylstibine (4) has been obtained in 89% yield by reaction of dijodomethylstibine (3) with phenylmagnesium bromide.
    Notes: Die Komplexe [HgX2·SbCH3(C6H5)2]2 mit X=Cl (5), Br (6), J (7) fallen bei der Vereinigung äquimolarer Mengen der Komponenten in Methanol- oder Aceton-Lösung aus. Dimere, halogenverbrückte Strukturen dieser Komplexe werden aus Infrarotspektren (300-33/cm) abgeleitet. Der Ligand Methyldiphenylstibin (4) wird durch Reaktion von Dijodmethylstibin (3) mit Phenylmagnesiumbromid in 89 proz. Ausbeute erhalten.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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