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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 14 (1989), S. 145-150 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An experimental study has been performed to determine the potential effect of buoyancy on the rate of propagation of a co-current smolder reaction through a porous solid fuel, and the range of flow velocities where buoyancy effects are significant. In the co-current smolder reaction, the fuel and oxidizer enter the reaction zone from the same direction. In the present experiments this is accomplished by initiating the reaction at the top of the fuel bed, α-cellulose packed at a void fraction 0.85, so that the smolder wave propagates downward opposing an upward forced flow of air. Since in a stratified density field, buoyancy is proportional to the product of gravity and density difference, buoyancy can be controlled by varying either the gravity vector or the gas density. In this study the latter method is followed, varying gas density through the ambient pressure at which the experiments are performed. The smolder velocity is measured for air flow rates varying from 0.2 to 6 gm-2s-1 at constant ambient pressures of 0.6, 0.8 and 1 atm. The results show that for flow rates larger than 1 gm-2s-1 the smolder velocity increases linearly with the air flow rate but is independent of pressure. The reaction peak temperature is weakly dependent on flow rate and independent of pressure. For the present experimental conditions the effect of buoyancy is only observed at very low air flow rates. The mechanisms by which it affects the smolder process appears to be by altering the transport of air to the reaction zone from upstream and downstream of the reaction.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 1975-02-01
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 3
    Publication Date: 2019-06-28
    Description: Temperature and velocity profiles are presented for cyclohexane, n-heptane, and iso-octane free, laminar, boundary layer, sooting, diffusion flames. Temperatures are measured with 3 mil Pt/Pt-13 percent Rh thermocouples. Corrected gas temperatures are derived by performing an energy balance of convection to and radiation from the thermocouple bead incorporating the variation of air conductivity and platinum emissivity with temperature. Velocities are measured using laser doppler velocimetry techniques. Profiles are compared with previously reported analytic temperature and velocity fields. Comparison of theoretical and experimental temperature profiles suggests improvement in the analytical treatment is needed, which accounts more accurately for the local soot radiation. The velocity profiles are in good agreement, with the departure of the theory from observation partially due to the small fluctuations inherent in these free flows.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: AIAA PAPER 86-0575
    Format: text
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  • 4
    Publication Date: 2019-06-28
    Description: The effect of buoyancy on the rate of spread of a concurrent smolder reaction through a porous combustible material is investigated theoretically and experimentally. In the experiments, buoyant forces are controlled by varying the density difference, and the smolder rate spread through porous alpha cellulose (0.83 void fraction) is measured as a function of the ambient air pressure. The smolder velocity is found to increase with the ambient pressure; extinction occurs when the buoyancy forces cannot overcome the drag forces, indicating that diffusion by itself cannot support the spread of a smolder reaction. Theoretical predictions are found to be in good qualitative agreement with the experimental results.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: IAF PAPER 85-289
    Format: text
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  • 5
    Publication Date: 2019-06-28
    Description: The objective of this section of the microgravity project is to identify key sets of low-gravity experiments which would critically compliment a larger set of more easily performed normal-gravity experiments to explain the phenomena found in smoldering combustion. It is planned to follow through on the conceptual design of these experiments by participating in the future in the fabrication of the refined apparatus and in the data collection and interpretation. Low-gravity experiments are appropriate for smoldering combustion because of the complexity of smoldering which requires every means possible to discriminate among the many chemical and physical mechanisms active in most smoldering combustion scenarios. Efforts will be primarily analytical, attempting to identify appropriate approximations and dominant dimensionless groups based on existing data and state-of-the-art combustion modelling. Transient stability questions such as ignition, extinction and the choices among charring, tarring, or flaming modes will be included.
    Keywords: ASTRONAUTICS (GENERAL)
    Type: NASA, Washington Microgravity Sci. and Appl. Program Tasks; p 184
    Format: text
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  • 6
    Publication Date: 2019-07-13
    Description: Two laser diagnostic techniques were used to measure soot volume fractions, number densities and soot particle radii in premixed propane/oxygen flat flames. The two techniques used were two wavelength extinction, using 514.5 nm to 632.8 nm and 457.9 nm to 632.8 nm wavelength combinations, and extinction/scattering using 514.5 nm light. The flames were fuel-rich (equivalence ratios from 2.1 to 2.8) and had cold gas velocities varying from 3.4 to 5.5 cm/s. Measurements were made at various heights above the sintered-bronze, water-cooled flat flame burner with the equivalence ratio and cold gas velocity fixed. Also, measurements were made at a fixed height above the burner and fixed cold gas velocity while varying the equivalence ratio. Both laser techniques are based on the same underlying assumptions of particle size distribution and soot optical properties. Full Mie theory was used to determine the extinction coefficients K sub ext, and the scattering efficiencies, Q sub vv. Temperature measurements in the flames were made using infrared radiometry. Good agreement between the two techniques in terms of soot particle radii, number density and volume fraction was found for intensity ratios (I/I sub o) between 0.1 and 0.8. For intensity ratios higher or lower than this range, the differences in extinction coefficients at the wavelengths chosen for the two-wavelength method are too small to give accurate results for comparing particle radii and number densities. However, when comparing only soot volume fractions, the agreement between the two techniques continued to be good for intensity ratios up to 0.95.
    Keywords: INORGANIC AND PHYSICAL CHEMISTRY
    Type: ASME Winter Annual Meeting; Nov 27, 1988 - Dec 02, 1988; Chicago, IL; United States
    Format: text
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