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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 80 (1976), S. 1676-1684 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 67 (1963), S. 1011-1015 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 67 (1963), S. 1469-1472 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 30 (1987), S. 386-392 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A test-particle method was developed to estimate the conditions that lead to collision-dominated evaporation during pulse heating of a solid surface in vacuum. The method consists of calculating the number density of evaporated molecules above the surface neglecting collisions and then sending a test particle through this cloud. The probability that the test particle escapes from the cloud without making a collision is the measure of the importance of intermolecular collisions during the blow off. The method is applied to heating of a ∼1 cm diam spot on the surface with a heat pulse of ∼1 msec duration. These conditions characterize laboratory laser vaporization experiments intended to measure the vapor pressures of refractory solids at very high temperatures. The principal variable which determines the escape probability is the maximum surface temperature during the transient. When applied to laser heating of uranium dioxide, collisional effects in the vapor are predicted to begin at a maximum surface temperature between 2600 and 2800 K.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Naturwissenschaften 67 (1980), S. 61-71 
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Notes: Abstract The most difficult problems affecting commercialization of the liquid-metal fast breeder reactor (LMFBR) concern the behavior of its materials of construction in the thermal and irradiation environment in which the device must operate. The responses which these conditions provoke in the fuel, cladding, and core structures depend upon complex interactions of many physical and chemical processes.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 14 (1968), S. 235-241 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The extraction of lanthanum and barium from single falling drops of the uranium-chromium eutectic into magnesium was studied at 1,000°C. Because of the short contact times involved, the data best fit the stagnant diffusion model for lanthanum. For barium, the fraction extracted was governed by external resistance of the magnesium phase. Drop velocities were adequately represented by the Hu-Kintner correlation.
    Additional Material: 7 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 693-699 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rates of the reaction of chlorine gas with uranium tetrachloride dissolved in the lithium chloride-potassium chloride eutectic have been studied in a wetted-rod contactor. The reaction was studied at temperatures from 400° to 700°C., uranium tetrachloride concentrations of 1 to 3 wt. %, and chlorine partial pressures of 0.25 to 1 atm. The production of uranium hexachloride appears to be limited by the equilibrium of the reaction UCL4 (solution) + Cl2 (g) = UCl6 (solution) at the interface and by U+4 diffusion in the liquid phase.
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 346-347 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 152-159 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The distribution of nitric acid between water and solutions of tributyl phosphate in n-hexane has been measured over a greater range of acid and tributylphosphate concentrations than have been reported previously.The partitioning of nitric acid between water and tributylphosphate-hexane solvents has been satisfactorily explained on the basis of the commonly accepted equilibrium complexing reaction, with this modification: The over-all aqueous-to-organic reaction is subdivided into the distribution of uncomplexed nitric acid and an organic phase complexing reaction. This alteration is found necessary to account for the behavior of the partitioning data of dilute acid over the entire tributylphosphate-hexane range. The residual discrepancy between the theory and the data can be qualitatively attributed either to modest nonideality of the organic phase or to the effect of the varying water content of the solvent on the distribution coefficient of uncomplexed nitric acid.The sparse data on water extraction by tributylphosphate-hexane solvents are not amenable to the same type of analysis, even though a type of complexing similar to that found for nitric acid has been previously proposed. The interaction between water and tributylphosphate appears to be stronger than that normally attributed to nonideality but weaker than a true chemical complex.
    Additional Material: 8 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 175-176 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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