ISSN:
0887-624X
Keywords:
polyoxymethylene
;
trioxane
;
ethylene oxide
;
acetal copolymer
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Recently, we have observed the following phenomena during the copolymerization of trioxane and ethylene oxide using a boron trifluoride initiator. In almost all of the polymerization cases, all polymers were soluble in a p-chlorophenol-tetrachloroethane mixed solvent at 90°C. However, in some polymerization cases, a small portion of the polymer was insoluble at this temperature, and this mixed solvent-insoluble fraction showed a higher melting point than that of the other fractions. Scanning electron microscope (SEM) photographs of the polymer showed that a highly fibrous structure was formed for the mixed solvent-insoluble fraction, and this highly packed structure is thought to be the origin of the high melting fraction. The nature of this high melting fraction was further examined using X-ray diffraction and Raman spectra. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 2479-2486, 1997
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
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