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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 2513-2527 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dicumylperoxide (DCPO) promoted functionalization of an ethylene-propylene copolymer (EPR) by means of dibutyl meleate (DBM) has been studied in bulk at constant reactant composition (100 : 10 : 1 by wt EPR-DBM-DCPO) in the range of temperature from 140 to 200°C. The reactants have been premixed in a Brabender-like apparatus at 90°C in which no decomposition of the radical initiator could occur. This was done in the frame of a general discussion of polyolefin functionalization, to assure the homogeneity of the reactant mixture before the reaction occurred.The kinetics of the reaction followed by an infrared (IR) technique was carried out according to two different procedures: a static one in a thermostatic bath and a dynamic one in the same mixer used for the premixing step. The kinetics in the two cases are very comparable, and a common activation energy of 40 kcal/mol has been measured. Some minor differences exist, however, which are very interesting from a scientific point of view.The kinetics of EPR degradation during the reaction has been indirectly monitored by means of solution viscosimetry. The results have been compared with the reaction kinetics.A thorough discussion of the proposed mechanism for grafting and degradation reactions has been also provided.Further work is in progress to analyze the effect of the EPR copolymer and of reactant composition on the functionalization and degradation reactions.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 1124-1134 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The morphology and mechanical properties of binary blends of nylon 6 (N6), as the major component, and ethylene-methacrylic acid copolymers (E/MAA), as the minor component, have been analyzed. It was found that the methacrylic acid content of the copolymer used as the second component has a profound effect upon the properties of the resulting blends. In particular, with increasing methacrylic acid content, the size of the domains of the E/MAA dispersed phase in the N6 matrix decreased in a regular fashion while the ultimate tensile properties increased regularly. This behavior has been attributed to a series of chemical and physico-chemical interactions taking place between the two components. The interactions are due to the presence of the acid functionality on the copolymer and do not occur when this functionality is absent. Chemical analysis of the blends was performed to confirm that chemical modification took place during the blending process.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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