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  • 1
    Series available for loan
    Series available for loan
    Geology of the Shaviovik and Sagavanirktok Rivers region, Alaska (1961)
    Washington, DC : Unites States Gov. Print. Off.
    Associated volumes
    Details Availability
    Call number: SR 90.0002(303-D)
    In: Professional paper
    Type of Medium: Series available for loan
    Pages: S. 169-222 + 6 pl.
    Series Statement: U.S. Geological Survey professional paper 303-D
    Language: English
    Location: Lower compact magazine
    Branch Library: GFZ Library
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  • 2
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    Proteins identified from the black smoker chimney Inferno hydrothermal vent plume meta-proteome - replicate Av1 - on the Axial seamount off the coast of Washington in 2011. (2016)
    Biological and Chemical Oceanography Data Management Office (BCO-DMO). Contact: bco-dmo-data@whoi.edu
    Details
    Publication Date: 2022-10-31
    Description: Dataset: Inferno vent plume proteins-Av1
    Description: Proteins identified from the black smoker chimney Inferno hydrothermal vent plume waters at Axial Seamount, an active volcano along the Juan de Fuca Ridge spreading center, were identified using tandem mass spectrometry (MS/MS). These data are reported as Supplementary Table 3 and discussed in the on-line publication “Sulfur oxidizers dominate carbon fixation at a biogeochemical hot spot in the dark ocean” by Mattes, et al., 2013. doi for that publication: 10.1038/ismej.2013.113. This is the first of two replicate datasets. For a complete list of measurements, refer to the supplemental document 'Field_names.pdf', and a full dataset description is included in the supplemental file 'Dataset_description.pdf'. The most current version of this dataset is available at: http://www.bco-dmo.org/dataset/627835
    Description: NSF Ocean Sciences (NSF OCE) OCE-1232840
    Keywords: Bacteria ; Proteomics ; Hydrothermal
    Repository Name: Woods Hole Open Access Server
    Type: Dataset
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  • 3
    Electronic Resource
    Electronic Resource
    Syntheses and gastric acid antisecretory properties of the H2-receptor antagonist N-[3-[3-(1-piperidinylmethyl)phenoxy]propyl]thieno[3,4-d]isothiazol-3-amine 1,1-dioxide and related derivatives (1988)
    s.l. : American Chemical Society
    Journal of medicinal chemistry 31 (1988), S. 1480-1486 
    Details
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/jm00402a039
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  • 4
    Electronic Resource
    Electronic Resource
    GAUSSIAN-2 calculations of the electron affinities of PCln and POCln (1999)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 111 (1999), S. 3309-3310 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The results of GAUSSIAN-2 calculations are presented for the total energies and zero-point energies of neutral and anionic PCln and POCln (n=1–3), from which adiabatic electron affinities (EA) are determined for the ground-state neutral species. The calculations show that EA(POCl2)〉EA(Cl), by 0.11 eV, and that EA(PCl3) deduced from collisional ionization experiments is probably too low by 0.4 eV. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.479657
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  • 5
    Electronic Resource
    Electronic Resource
    Chemistry of PO−, PO2−, and PO3− in the gas phase (1998)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 4126-4127 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Rate constants have been measured for reactions of the small oxyphosphorus anions PO−, PO2−, and PO3− with a selection of reactant neutrals at 300 K using a selected ion flow tube instrument. The PO− anion was the most reactive, abstracting an oxygen atom from O2, NO, CO2, and NO2 with rates below collisional. Of the neutrals studied, only NO2 transferred an O atom to PO2−, demonstrating that NO2 can provide a route from PO− to PO3− through PO2−. PO2− was found to react with WF6 through fast charge transfer, and with H2O by slow clustering. The only observed reaction found for the highly stable PO3− anion was slow clustering with H2O.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.477015
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  • 6
    Electronic Resource
    Electronic Resource
    Formation of CF3O− in the gas phase (1999)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 110 (1999), S. 8436-8442 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report experimental studies of the formation of CF3O− by ion-molecule and electron attachment reactions, and theoretical investigations of the structure and energetics of CF3O− and its neutral counterpart CF3O. The anion CF3O− is formed from the rapid attachment of free electrons to its neutral dimer, (CF3O)2. Potential sources of CF3O− through ion-molecule reactions of CF3− and F− were surveyed. CF3O− is formed in the bimolecular ion-molecule reaction of CF3− with SO2 and the third-order association reaction of F− with CF2O. In addition, rate constants for the reactions of CF3− with a variety of neutral compounds were measured. A number of cases were found in which formation of CF3O− was energetically allowed but was not observed. The potential energy surfaces of CF3O and CF3O− have been investigated using a variety of density functional theory (DFT) techniques. The ground-state minimum energy structure of CF3O was found to be a 2A′ Jahn–Teller distorted Cs-symmetry structure, while for the anion the ground state is 1A1 with a C3v-symmetry minimum. A search for other low-energy minima for CF3O− was unsuccessful. The DFT methods support a value for the adiabatic electron affinity of CF3O near 4.1 eV. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.478753
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  • 7
    Electronic Resource
    Electronic Resource
    Electron attachment to PCl3 and POCl3, 296–552 K (1998)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 578-584 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Rate constants for electron attachment to PCl3 and POCl3 have been measured over the temperature range 296–552 K in 135 Pa of helium gas, using a flowing-afterglow Langmuir-probe apparatus. Electron attachment to PCl3 is dissociative, producing only Cl− ions in this temperature range. The rate constant is 6.4±1.6×10−8 cm3 s−1 at 296 K and increases with temperature in a way that may be described by an activation energy of 43±10 meV. Electron attachment to POCl3 is a richer process in which a nondissociative channel (POCl3−) competes with two dissociative ones (POCl2− and Cl−). The rate constant for electron attachment to POCl3 is 1.8±0.4×10−7 cm3 s−1 at 296 K and is relatively temperature independent in our temperature range. POCl2− is the major product over the entire temperature range. Ab initio MP2 and MP4 calculations have been carried out on ground-state neutral and anionic PCln and POCln for n=1–3. The calculated adiabatic electron affinities agree with experimental estimates where available. The calculations yield C3v structural symmetries for PCl3 and POCl3, and Cs symmetries for PCl3− and POCl3−. The degree of distortion between the respective neutrals and anions is explored in the calculations, and the implications for electron attachment reactions are outlined. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.476594
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  • 8
    Electronic Resource
    Electronic Resource
    Rate constants for the reactions of O+ with N2 and O2 as a function of temperature (300–1800 K) (1997)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 3540-3544 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have studied the rate constants for the reaction of O+ with N2 over the temperature range 300–1600 K and the reaction of O+ with O2 over the range 300 to 1800 K. The results are in good agreement with previous measurements made up to 900 K. The rate constant for the O+ reaction with N2 shows a minimum in the temperature range 1100–1300 K. The increase above this temperature is due to N2 v=2 becoming populated. The rate constant for O++O2 shows a minimum in the 800–1100 K range. Comparing to previous drift tube measurements allows the rate constant for O2 (v〉0) to be derived. The v〉0 rate constant is approximately five times larger than the v=0 rate constant. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.473450
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  • 9
    Electronic Resource
    Electronic Resource
    The gas-phase acidity of H3PO4 (1997)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 3545-3547 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The gas-phase acidity (free energy of deprotonation, ΔGacid0) of H3PO4, orthophosphoric acid, was determined both experimentally and theoretically for the first time. Ion-molecule bracketing experiments yielded the result 1372 kJ mol−1〉ΔGacid0(H3PO4)〉1331 kJ mol−1. The most reliable theoretical result, ΔGacid0H(H3PO4)=1343 kJ mol−1, is in agreement with experiment and was obtained using Brueckner methods with large basis sets. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.473465
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  • 10
    Electronic Resource
    Electronic Resource
    Rate coefficients for the endothermic reactions C+(2P)+H2(D2)→CH+(CD+)+H(D) as functions of temperature from 400–1300 K (1997)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 106 (1997), S. 10145-10152 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We have measured the bimolecular rate coefficients for the reactions of C+(2P) with H2 and D2 as functions of temperature from 400 to 1300 K using a high temperature flowing afterglow apparatus. The temperature dependences of these rate coefficients are accurately fit by the Arrhenius equation, with activation energies equal within experimental uncertainty to the reaction endothermicities. Internal energy dependences have been deduced by combining the present data with previous drift tube and ion beam measurements. We found that reactant rotational energy and translational energy are equally effective in surmounting the energy barrier to reaction, and that vibrational excitation of the neutral reactant to the v=1 state enhances the rate coefficients by a factor of ∼1000 for the reaction with H2 and by ∼6000 for the reaction with D2 at temperatures of 800 and 500 K, respectively. This vibrational enhancement is larger than the enhancement that would be produced if the same amount of energy were put into translational and/or rotational modes of the reactants. In addition, rate coefficients have been derived for the three-body association reaction of C+(2P) with H2 in a helium buffer over the temperature range 300–600 K. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.474093
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