ISSN:
1572-8927
Keywords:
Acid dissociation
;
potentiometry
;
calorimetry
;
tert-butyl alcohol-water mixtures
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Standard Gibbs free energies, enthalpies, and entropies for the dissociation of various aliphatic carboxylic acids are obtained through potnetiometric and calorimetric measurements in water-tert-butyl alcohol mixtures. Results are discussed in terms of solvent structural effects for the proton exchange reaction and in terms of the compensation law to explain enthalpic and entropic effects.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00646481
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