ISSN:
1572-879X
Keywords:
Metathesis
;
alkenes
;
photoreduction
;
laser
;
molybdenum oxide
;
silica
;
silicaalumina
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Photoreduction of MoO3/SiO2 and MoO3/SiO2·Al2O3 catalysts in CO with a laser beam at 308 nm resulted, after addition of cyclopropane to form the active sites, in a high activity for alkene metathesis. Both catalyst systems are active for normal alkenes, e.g. propene, and for functionalized alkenes, e.g. methyl oleate, already at room temperature.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00812138
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