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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 27 (1989), S. 331-332 
    ISSN: 0887-6258
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 407-414 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Naturally occurring polyphenol(condensed tannin)-phenol-formaldehyde copolymer matrix based cation exchange resins have been successfully used as a solid catalyst (in H+ ion form) in the inversion of sucrose and hydrolysis of methyl acetate. Apart from the normal advantages of the solid catalyst over the acid catalysts in the solution phase, the values of the activation energy, entropy, and enthalpy of activation of the reactions involved reveal that the resins prepared acted as a catalyst with characteristics comparable to those of the commercially available resins based on a styrene-DVB matrix. The resins have also been successfully used for softening of hard water and enrichment of metal ion concentration from very dilute solutions. © 1995 John Wiley & Sons, Inc.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 42 (1991), S. 2499-2508 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Most of the commercially available ion exchange resins at present are either styrene-DVB-based or phenol-based and these are dependent on petroleum products. In view of the ever increasing demand for ion exchange resins and the petroleum crisis, the cost of these resins is going up in leaps and bounds. Although work on ion exchange resins based on naturally occurring tannins and similar materials have been reported in the literature, their low stability, insufficiently low exchange capacity, and similar other disadvantages come in the way of commercial exploitation of these products. In the present communication, studies on preparation and properties, viz., exchange capacity, hydration, swelling, stability, etc. of some effective cation exchange resins which have been obtained from a renewable natural resource of polyphenolic nature and some small proportion of phenol have been reported. The resins studied are stable and of moderately high exchange capacity (2-3 meq/g). Substituting phenol with low-priced renewable polyphenolic material, the resultant copolymer matrix after sulfonation gives ion exchange resins which are quite economic. Their properties are comparable with the commercial resins available in the market.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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