ISSN:
1573-9171
Keywords:
ion background
;
aquation rate
;
[CrCl3(H2O)3)]
;
equilibrium constants
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The influence of change in ion background on the aquation rate constants of [CrCl3(H2O)3)] was studied spectrophotometrically at 25°C over a broad range of ionic strengths (up to several moles/liter). The electrolytes KBr, KCl, NaClO4, NaCl, NaBr, NaNO3, HClO4, HCl, LiClO4, CaCl2, LaCl3, and ethanol were used. It is shown that the rate constant decreases with increasing electrolyte concentration in the electrolytic media (to 0.3 log unit in some of them), while increasing in ethanol media with increasing content of the alcohol.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01150733
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