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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 61 (1996), S. 1717-1729 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The blown films of high-density polyethylenes with unimodal and bimodal molecular weight distribution were prepared under several processing conditions, and their morphologies were extensively characterized. The high molecular weight tail (MW 〉 ∼ 106) of the molecular weight distribution seems to play a critical role on the morphology of blown highdensity polyethylene films irrespective of the molecular weight distribution mode of the resins. As the content of high molecular weight species increased, the tendency for high stress-crystallization increased and the network structure of lamellar stacks was better developed. The intercrystalline connectivity along the normal direction of lamellar stacks was higher than that along the transverse direction of lamellar stacks. © 1996 John Wiley & Sons, Inc.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 60 (1996), S. 2469-2479 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: High-density polyethylenes with unimodal and bimodal molecular weight distribution have been fractionated according to crystallizability using preparative temperature rising elution fractionation. The molecular structure and thermal properties of the fractions with their whole polymers have been characterized. The average short chain branching content of the fractions obtained ranged from 0 to 8 branches per 1000 carbon atoms while that of the whole polymers is about 2 branches per 1000 carbon atoms. The bimodal resins have a slightly higher frequency of short chain branch in higher molecular weight species than in those of the unimodal resins. The short chain branching distribution as well as the low molecular weight species in the fractions seem to be important parameters to determine thermal behavior of the fractions. The fractions with the short chain branching content above 3 branches per 1000 carbon atoms showed a significantly different thermal behavior from those with less than 3 branches per 1000 carbon atoms. © 1996 John Wiley & Sons, Inc.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 1999-08-01
    Print ISSN: 0927-7757
    Electronic ISSN: 1873-4359
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Elsevier
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