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  • 1
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    PANGAEA
    In:  Supplement to: Thompson, Patricia M E; Kempton, Pamela D; White, Rosalind V; Kerr, Andrew C; Tarney, J; Saunders, Andrew D; Fitton, J Godfrey; McBirney, A (2003): Hf-Nd isotope constraints on the origin of the Cretaceous Caribbean plateau and its relationship to the Galápagos plume. Earth and Planetary Science Letters, 217(1-2), 59-75, https://doi.org/10.1016/S0012-821X(03)00542-9
    Publication Date: 2023-06-27
    Description: Formation of the Cretaceous Caribbean plateau, including the komatiites of Gorgona, has been linked to the currently active Galápagos hotspot. We use Hf-Nd isotopes and trace element data to characterise both the Caribbean plateau and the Galápagos hotspot, and to investigate the relationship between them. Four geochemical components are identified in the Galápagos mantle plume: two 'enriched' components with epsilon-Hf and epsilon-Nd similar to enriched components observed in other mantle plumes, one moderately enriched component with high Nb/Y, and a fourth component which most likely represents depleted MORB source mantle. The Caribbean plateau basalt data form a linear array in Hf-Nd isotope space, consistent with mixing between two mantle components. Combined Hf-Nd-Pb-Sr-He isotope and trace element data from this study and the literature suggest that the more enriched Caribbean end member corresponds to one or both of the enriched components identified on Galápagos. Likewise, the depleted end member of the array is geochemically indistinguishable from MORB and corresponds to the depleted component of the Galápagos system. Enriched basalts from Gorgona partially overlap with the Caribbean plateau array in epsilon-Hf vs. epsilon-Nd, whereas depleted basalts, picrites and komatiites from Gorgona have a high epsilon-Hf for a given epsilon-Nd, defining a high-epsilon-Hf depleted end member that is not observed elsewhere within the Caribbean plateau sequences. This component is similar, however, in terms of Hf-Nd-Pb-He isotopes and trace elements to the depleted plume component recognised in basalts from Iceland and along the Reykjanes Ridge. We suggest that the Caribbean plateau represents the initial outpourings of the ancestral Galápagos plume. Absence of a moderately enriched, high Nb/Y component in the older Caribbean plateau (but found today on the island of Floreana) is either due to changing source compositions of the plume over its 90 Ma history, or is an artifact of limited sampling. The high-epsilon-Hf depleted component sampled by the Gorgona komatiites and depleted basalts is unique to Gorgona and is not found in the Caribbean plateau. This may be an indication of the scale of heterogeneity of the Caribbean plateau system; alternatively Gorgona may represent a separate oceanic plateau derived from a completely different Pacific plume, such as the Sala y Gomez.
    Keywords: 15-146; 15-151; 15-152; AGE; Caribbean Sea/BASIN; Caribbean Sea/CONT RISE; Caribbean Sea/RIDGE; Deep Sea Drilling Project; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Event label; Glomar Challenger; Hafnium; Inductively coupled plasma - mass spectrometry (ICP-MS); Leg15; Lutetium; Lutetium-176/Hafnium-177; Mass spectrometer Finnigan MAT 262; Neodymium; Neodymium-143/Neodymium-144 ratio; Samarium; Samarium-147/Neodymium-144 ratio; Sample code/label; ε-Hafnium; ε-Neodymium (T)
    Type: Dataset
    Format: text/tab-separated-values, 55 data points
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  • 2
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Earth and Planetary Sciences 12 (1984), S. 337-357 
    ISSN: 0084-6597
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Earth and Planetary Sciences 6 (1978), S. 437-456 
    ISSN: 0084-6597
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 95 (1987), S. 4-20 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Following its birth on the 20th of February 1943, the Mexican volcano Paricutin discharged a total of 1.38 km3 of basaltic andesite and andesite before the eruption came to an end in 1952. Until 1947, when 75% of the volume had been erupted, the lavas varied little in chemical or isotopic composition. All were basaltic andesites with 55 to 56% SiO2, δ 18O of +6.9 to 7.0, and 87Sr/86Sr ratios close to 0.7038. Subsequent lavas were hypersthene andesites with silica contents reaching 60%, δ18O values up to +7.6, and 87Sr/86Sr of 0.7040 to 0.7043. The later lavas were enriched in Ba, Rb, Li, and K2O and depleted in MgO, Cu, Zn, Cr, Ni, Sr, and Co. The isotopic and other chemical changes, which appeared abruptly over a few months in 1947, are interpreted as the result of tapping a sharply zoned and density stratified magma chamber. Xenoliths of partially fused felsic basement rocks in the lavas have silica contents greater than 70%, δ 18O of +5.6 to 9.9 and 87Sr/86Sr between 0.7043 and 0.7101. In many respects they resemble samples of basement rocks collected from nearby outcrops. Three analysed samples of the latter have silica contents of 65 to 67%, δ 18O of +7.7 to 8.6, and 87Sr/86Sr between 0.7047 and 0.7056. These new data provide strong support for the original interpretations of Wilcox (1954), who explained the chemical variations by a combination of fractional crystallization and concurrent assimilation of up to 20 weight % continental crust. Except for a few trace elements, particularly Ba, Sr, and Zr, the chemical and isotopic compositions of the xenoliths and basement rocks that crop out nearby match the type of contaminant required to explain the late-stage lavas. Some of the discrepancies may be explained by postulating a contaminant that was older and richer in Ba, Sr, and Zr than those represented by the analysed xenoliths. Others can be attributed to chemical changes accompanying disequilibrium partial melting, contact metamorphism, and meteoric-hydrothermal alteration of the country rock. Many of the xenoliths show evidence of having been affected by such processes. The lavas were erupted from a zoned magma chamber that had differentiated by liquid fractionation prior to the eruption. The order of appearance of the lavas can be explained in terms of withdrawal of stratified liquids of differing densities and viscosities.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The oldest known and best documented of the drowned islands, referred to here as the 85°40'W seamount, seems to have formed over the hotspot at least 9 Myr ago. This small seamount is the middle of three similar east-west aligned edifices, previously surveyed along 2° S ...
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 76 (1981), S. 265-284 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Results of this research and the earlier work of Wager and his colleagues indicate that contamination influenced the overall character of the Marginal Border Group of the Skaergaard intrusion. Precambrian gneisses were a major source of contamination and are identifiable as xenoliths in the Marginal Border. A variety of other xenoliths occur with a wide compositional range. The range of K D values for partitioning of Fe and Mg in coexisting pyroxene pairs in xenoliths from various parts of the Marginal Border, and in hornfelses adjacent to it, is consistent with temperatures that rose steeply inward. Temperatures estimated on the basis of compositions of coexisting pyroxenes are also consistent with dehydration that exceeded the stability of amphibole (≧850°C). The texturally compatible association of some granophyres with gneissic xenoliths suggests that both formed during melting. These observations suggest that there was a similar range of temperature for formation of xenoliths and granophyres. The xenoliths of gneisses have bulk rock compositional features which indicate that lithophilic constituents were removed, causing an increase in basic constituents upon assimilation of the gneissic precursors. If we assume that granophyres and xenoliths of gneisses represent a consanguineous set formed by a fusion process from gneiss, enrichment and depletion factors for excluded trace elements are complementary and generally less than 10. Allowable enrichment in granophyres by crystal fractionation using the average for a large number of chilled marginal gabbro analyses as an initial composition, is also less than 10 for the same elements. The calculated low factors for enrichment of lithophile elements in granophyres by both mechanisms favor the hypothesis of partial melting of gneiss.
    Type of Medium: Electronic Resource
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  • 7
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    Publication Date: 2015-02-13
    Description: Hydrothermal experiments were conducted at ca. 1 to 7000 bars and 700 to 1250 °C in 121 rhyolitic to basaltic systems to determine Cl solubility in silicate melts, i.e., the maximum Cl concentration in melts that are saturated in a hydrosaline liquid with or without an aqueous or aqueous-carbonic vapor. The Cl concentration of melts increases with the Cl contents of the fluid unless the melt coexists with vapor plus hydrosaline liquid at fixed pressure and temperature; this phase assemblage buffers the Cl content of each phase with increasing Cl in the system. The Cl content of fluid(s)-saturated melts is independent of the CO 2 concentration of the saline liquid ± vapor with up to 21 wt% CO 2 in the fluid(s). The experiments show that Cl dissolution in aluminosilicate melts increases with temperature and pressure. Chlorine solubility is also a function of melt composition; it increases with the molar ([Al 1/2 +Ca 1/2 +Mg 1/2 +Na]/Si) of the melt. These experimental data have been integrated with results involving 41 other experiments ( Webster and De Vivo 2002 ) to develop a broadly expanded model that supports calculation of Cl solubility in 163 aluminosilicate melts. This empirical model applies to Cl dissolution in melts of most silicate magmas at depths as great as 25 km. It determines the exsolution of hydrosaline liquid, with or without a coexisting vapor, as magmas ascend from depth, cool, crystallize, and differentiate from mafic to felsic compositions. In combination with H 2 O solubility models, our model supports determination of H 2 O-Cl solubility relations for most aluminosilicate magmas and is useful for barometric estimations based on silicate melt inclusions containing low CO 2 and moderate to high-Cl concentrations. The model is applied to the phase relations of fluids in volatile-enriched magmas of Augustine volcano, Alaska. The Cl and H 2 O concentrations of melt inclusions from 14, basaltic to dacitic eruptive units are compared with modeled solubilities of Cl and H 2 O in Augustine melts. The majority of these eruptions involved magmas that first exsolved aqueous to aqueous-carbonic vapors when the melts were dacitic in composition (i.e., before the residual melts in these magmas had evolved to felsic compositions) and well prior to the eruptions. Hydrosaline liquid with or without a vapor phase exsolved from other, more-felsic fractions of Augustine melts at low, near-surface pressures of several tens of bars.
    Print ISSN: 0003-004X
    Electronic ISSN: 1945-3027
    Topics: Geosciences
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  • 9
    Publication Date: 1978-05-01
    Print ISSN: 0084-6597
    Electronic ISSN: 1545-4495
    Topics: Geosciences , Physics
    Published by Annual Reviews
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  • 10
    Publication Date: 1984-01-01
    Print ISSN: 0084-6597
    Electronic ISSN: 1545-4495
    Topics: Geosciences , Physics
    Published by Annual Reviews
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