ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound consists of a neutral [Co(C2H)(C3H9P)4] unit, with the ligands arranged in a distorted trigonal bipyramidal configuration, retaining threefold axial symmetry. The C[triple-bond]CH unit occupies an axial position, with a C[triple-bond]C bond length of 1.185 (6) Å. This compound represents the first structurally characterized example of a cobalt(I)–ethynyl complex.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270195010304
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