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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The nanoscale crystalline and amorphous phases obtained by partial crystallization of an amorphous phase in rapidly solidified Fe90Nd7−xZrxB3 alloys were found to exhibit rather good hard magnetic properties in the composition range below 3 at. % Zr and good soft magnetic properties in the range above 4 at. % Zr. The hard magnetic alloys consist of nanoscale bcc–Fe and bct–Fe14Nd2B particles surrounded by the remaining amorphous phase, while the soft magnetic alloys are composed of bcc–Fe and remaining amorphous phases. The particle size is measured to be about 20 nm for the bcc–Fe phase and 15 nm for the Fe14Nd2B phase for a the former alloys and about 10 nm for the bcc–Fe phase for the latter alloys. The volume fraction of the remaining amorphous phase is evaluated to be about 20 to 30 at. % and the Nd and Zr contents are much higher than the nominal concentrations for the hard and soft magnetic alloys from the high-resolution TEM images and nanobeam compositional analyses. The remanence (Br), intrinsic coercivity (iHc), and maximum energy product are 1.24 T, 200 kA/m, and 88 kJ/m3, respectively, for the nanocrystalline Fe90Nd5Zr2B3 alloy annealed for 180 s at 1023 K, while the saturation magnetization (Bs), coercivity (Hc), and permeability at 1 kHz are 1.63 T, 16 A/m, and 7000, respectively, for the nanocrystalline Fe90Nd2Zr5B3 alloy annealed for 180 s at 923 K.The high Br and Bs values are presumably due to the magnetic coupling between bcc–Fe particles via the ferromagnetic intergranular amorphous phase and the large iHc for the alloy containing more than 4 at. % Nd is due to the exchange magnetic interaction betweeen Fe14Nd2B particles via ferromagnetic bcc–Fe and amorphous phases. The appearance of the rather good hard and soft magnetic properties for the same alloy series containing the high Fe content is extremely important for future development of manocrystalline hard and soft magnetic materials. © 1996 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 5472-5472 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have recently succeeded in producing good soft magnetic properties and high saturation magnetic density (Bs) for nanocrystalline Fe-M-B (M=Zr, Hf, or Nb) ternary alloys prepared by melt spun and sputtered technic. The alloys have the mixed structure consisting of α-Fe particles with 10–20 nm in size embedded in a remaining amorphous phase. The nanocrystalline bcc Fe90Zr7B3, Fe89Hf7B4 and Fe84Nb7B9 alloy ribbons subjected to the optimum annealing exhibit high Bs of 1.5–1.7 T as well as high effective permeability (μe) of 22 000–32 000 at 1 kHz. The soft magnetic properties of the nanocrystalline Fe-M-B alloys were found to be improved by adding small amounts of Cu and by optimizing the chemical composition. The addition of Cu to the alloys decreases the bcc grain size. The excellent soft magnetic properties (high μe of 100 000 at 1 kHz combined with high Bs of 1.53 T) can be achieved in the region where small grain size as well as nearly zero magnetostriction are obtained, which is attained in the compositional range around Fe84Nb3.5Zr3.5B8Cu1. The soft magnetic properties can be further improved by preannealing before crystallization treatment, probably resulting from the decrease in the distribution of the grain size at the crystallized state. Consequently, the μe reaches the maximum value of 120 000 for the nanocrystalline Fe84Nb3.5Zr3.5B8Cu1 alloy. © 1996 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 7100-7102 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The compositional dependence of the soft magnetic properties of the nanocrystalline Fe–Zr–Nb–B alloys has been investigated. The magnetostriction (λs) and the grain size of the (Fe90Zr7B3)1−x(Fe84Nb7B9)x alloys, which are two typical ternary alloys mixed with the best soft magnetic properties, show intermediate values between those of the Fe90Zr7B3 with negative λs and the Fe84Nb7B9 with positive λs. However, the soft magnetic properties of the Fe–(Zr, Nb)7–B alloys are inferior to those of the Fe90Zr7B3 and the Fe84Nb7B9 alloys. The best soft magnetic properties have been obtained at Zr+Nb=6 at. %. The Fe85.5Zr2Nb4B8.5 alloy shows a high μe of 60 000 at 1 kHz, a high Bs of 1.64 T, and zero λs, simultaneously. The alloy also exhibits a very low core loss of 0.09 W/kg at 1.4 T and 50 Hz, which is extremely lower than that of Fe–Si–B amorphous alloys. The nanocrystalline Fe–Zr–Nb–B alloys with improved soft magnetic properties are therefore suitable for pole transformers. © 2000 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 5127-5129 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effect of the addition of Ti, V, Cr, and Mn on the magnetic properties of a nanocrystalline soft magnetic Fe–Zr–B alloy has been investigated. The addition of the elements increases both the crystallization temperature and the grain size of α-Fe. After crystallization, these elements are observed in both the α-Fe grains and the residual amorphous matrix. It has been found that V is a useful element to control magnetostriction by keeping the saturation magnetic flux density (Bs) high. The simultaneous addition of V and Mn increases Bs. The alloys with high Bs, above 1.75 T, show good soft magnetic properties as well; the Fe90V1Zr6B3 alloy exhibits high Bs of 1.75 T and high permeability (μe) of 31 000, and the Fe89.5V0.5Mn1Zr6B3 alloy exhibits high Bs of 1.78 T and high μe of 23 000. These high Bs values are almost the same as that of a Fe-6.5 wt % Si alloy. The alloys also exhibit low core loss. Therefore, nanocrystalline Fe–V–(Mn)–Zr–B alloys are expected to be applied to power electronic devices such as power transformers. © 1999 American Institute of Physics.
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  • 5
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Microstructure, soft magnetic properties, and applications of high resistive Fe-M-O (M=Hf, Zr, rare-earth metals) were studied. The Fe-M-O films are composed of bcc nanograins and amorphous phases with larger amounts of M and O elements which chemically combine each other. Consequently, the amorphous phases have high electrical resistivity. The compositional dependence of magnetic properties, electrical resistivity, and structure have been almost clarified. For example, the high magnetization of 1.3 T, high permeability of 1400 at 100 MHz and the high electrical resistivity of 4.1 μΩ m are simultaneously obtained for as-deposited Fe62Hf11O27 nanostructured film fabricated by rf reactive sputtering in a static magnetic field. Furthermore, Co addition to Fe-M-O films improves the frequency characteristics mainly by the increase in the crystalline anisotropy of the nanograins. The Co44.3Fe19.1Hf14.5O22.1 film exhibits the quality factor (Q=μ′/μ′′) of 61 and the μ′ of 170 at 100 MHz as well as the high Is of 1.1 T. This frequency characteristics is considered to be superior to the other films already reported. The films also exhibit high corrosion resistance in an isotonic sodium chloride solution. Therefore, these films enable us to realize the high-frequency magnetic devices, such as thin-film inductors and transformers for microswitching converters and ultrahigh-density recording heads. © 1997 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 83 (1998), S. 6332-6334 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have developed a choke coil made of new nanocrystalline soft magnetic Fe–M–B (M=Zr, Nb) alloys ("NANOPERM™ " material) which exhibit high saturation magnetic induction (Bs), above 1.5 T, excellent soft magnetic properties and zero magnetostriction. A choke coil made of NANOPERM™ material exhibits good dc bias characteristics of inductance because of the high Bs. Furthermore, the choke coil made from NANOPERM™ material showed 1/3rd the temperature rise shown by a core made from Fe–Si–B amorphous alloy. The low core loss and high Bs of NANOPERM™ material allow the reduction of the core size. It is concluded that NANOPERM™ is suitable as a core material for choke coils. © 1998 American Institute of Physics.
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  • 7
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The thermal stability of the supercooled liquid region (ΔTx), defined by the difference between crystallization temperature (Tx) and glass transition temperature (Tg), and soft magnetic properties were investigated for Fe70Al5Ga2P12.65−xC5.75B4.6Six(x=0–4) and Fe77Al2.14Ga0.86P11−xC5B4Six(x=0–3) glassy alloys. The thermal stability, glass forming ability and effective permeability (μe) at 1 kHz are improved with the replacement of P by 1–3 at. % Si for Fe70Al5Ga2P12.65−xC5.75B4.6Six and by 1–2.6 at. % Si for Fe77Al2.14Ga0.86P11−xC5B4Six. The ΔTx and the maximum thickness for glass formation (tmax) reach maximum values of 60 K and 280 μm, respectively, for Fe70Al5Ga2P12.65−xC5.75B4.6Six and 34 K and 220 μm, respectively, for Fe77Al2.14Ga0.86P11−xC5B4Six at Si(at. %)/(Si(at. %)+P(at. %))=0.24. Core losses for Fe77Al2.14Ga0.86P8.4C5B4Si2.6 glassy alloy is much lower than that for amorphous Fe–Si–B alloy at the sheet thickness more than 70 μm. Therefore, it can be said that the Fe–Al–Ga–P–C–B–Si glassy alloys are useful for inductive applications because of their bulky shape and good soft magnetic properties. © 1998 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 83 (1998), S. 6861-6863 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A Mn–Zn ferrite with a grain size of about 2 μm has been developed for the transformer driven at around 1 MHz. The developed ferrite exhibits considerably lower core losses than a conventional Mn–Zn ferrite with a grain size of about 10 μm at a frequency of 0.5 to 2 MHz. The thin-type transformer using the developed ferrite driven at 1 MHz shows a high efficiency of more than 95% at an output power of 10 to 17 W and a much lower surface temperature rise than the transformer using the conventional ferrite. © 1998 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 83 (1998), S. 1967-1974 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An amorphous phase with a wide supercooled liquid region before crystallization was formed in Fe56Co7Ni7Zr10−xMxB20 (M=Nb or Ta, x=0–10 at. %) alloys by melt spinning. The glass transition temperature (Tg) and crystallization temperature (Tx) increase by the dissolution of 2% M and the degree of the increase is larger for Tx, leading to maximum ΔTx(=Tx−Tg) of 85 K at 2% Nb and 87 K at 2% Ta which are larger by about 20 K than the largest value for newly developed Fe–(Al, Ga)–(P,C,B,Si) amorphous alloys. The crystallization of the Nb-containing alloys occurs through two stages of amorphous (Am)→Am′+α-Fe+γ-Fe+Fe76Nb6B18 →α-Fe+γ-Fe+Fe76Nb6B18+Fe2Zr in the range less than about 6% Nb and Am→Am′+γ-Fe→γ-Fe+Co3Nb2B5+Ni8Nb in the range above 8% Nb. The change in the crystallization process with Nb content seems to reflect the easy precipitation of γ-Fe by the increase in the number of Fe–Nb pairs with weaker bonding nature as compared with the Fe–Zr pairs. The best soft magnetic properties were obtained at 2% Nb or 8% Ta. The saturation magnetization, coercive force, effective permeability at 1 kHz, and saturated magnetostriction in the annealed state for 300 s at 800 K are, respectively, 0.96 T, 2.0 A/m, 19 100, and 10×10−6 for the 10% Zr alloy, 0.75 T, 1.1 A/m, 25 000, and 12×10−6 for the 2% Nb alloy, and 0.85 T, 1.5 A/m 17 400, and 14×10−6 for the 8% Ta alloy. The Curie temperature is 531 K for the 2% Nb alloy and 538 K for the 8% Ta alloy. The success in synthesizing the new amorphous alloys with the wide supercooled liquid region and good soft magnetic properties is promising for future development as soft magnetic bulk amorphous alloys. © 1998 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science, Ltd
    Plant, cell & environment 26 (2003), S. 0 
    ISSN: 1365-3040
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: The photosynthetic rates under saturating CO2 conditions per unit of leaf-N content were higher in wheat than in rice. This suggested that ribulose-1,5-bisphosphate (RuBP) regeneration capacity is greater in wheat. Therefore, the biochemical factor(s) for this difference were examined between rice and wheat. Soluble protein-N, insoluble-N, and trichloroacetic acid (TCA) soluble-N contents were found not to differ between the two species. The activities of several Calvin cycle enzymes such as RuBP carboxylase, NADP-glyceraldehyde-3-phosphate dehydrogenase, phosphoglycerate kinase and chloroplastic fructose-1,6-bisphosphatase (cpFBPase) activities per unit of leaf-N content were all higher in wheat than in rice. Among them, cpFBPase activity was most highly correlated with CO2-saturated photosynthesis. The Vmax activity of sucrose-phosphate synthase (SPS) for UDP-glucose was almost the same between the two species and its Km value was a little lower in rice. Chlorophyll content and its a/b ratio did not differ. Cytochrome (Cyt) f content was greater in wheat, whereas coupling factor 1 content was greater in rice. Cyt f content was highly correlated with CO2-saturated photosynthesis, irrespective of the two species. The results thus suggested that higher RuBP regeneration capacity in wheat leaves is most closely related to a greater Cyt f content and that another candidate is cpFBPase.
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