Publication Date:
2015-10-17
Description:
The synthesis of [2.2]paracyclophane derivatives containing tetrathiafulvalene units has been accomplished by the coupling reaction of 4-([2.2]paracyclophan-4-yl)-1,3-dithiol-2-thione in the presence of trimethylphosphite. The 1,3-dithiol-2-thione derivative was in turn synthesized by the regioselective bromination of 4-acetyl[2.2]paracyclophane, then through the corresponding dithiocarbamates and 1,3-dithiolium salts. Beilstein J. Org. Chem. 2015, 11, 1917–1921. doi:10.3762/bjoc.11.207
Keywords:
dithiocarbamates1,3-dithiolium salts[2.2]paracyclophaneregioselective brominationstereoisomerstetrathiafulvalenes
Electronic ISSN:
1860-5397
Topics:
Chemistry and Pharmacology
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