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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of environmental contamination and toxicology 58 (1997), S. 475 -481 
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Archives of environmental contamination and toxicology 14 (1985), S. 363-388 
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract As a continuing part of the National Contaminant Biomonitoring Program, the U.S. Fish and Wildlife Service collected freshwater fish at 112 monitoring stations in 1978–1979 and 1980–1981. Three composite samples of three to five fish were collected at each of about half of the stations in odd-numbered years and at the other half in even-numbered years, and analyzed for lead, mercury, cadmium, arsenic, selenium, cooper, and zinc. The geometric means, minimum, and maximum of elemental concentrations (μg/g wet weight) during 1978–1979 and (in parentheses) during 1980–1981 were as follows: Pb 0.19, 0.10–6.73 (0.17, 0.10–1.94); Hg 0.11, 0.01–1.10 (0.11, 0.01–0.77); Cd 0.04, 0.01–0.41 (0.03, 0.01–0.35); As 0.16, 0.04–2.08 (0.14, 0.05–1.69); Se 0.46, 0.09–3.65 (0.47, 0.09–2.47); Cu 0.86, 0.29–38.75 (0.68, 0.25–24.10); and Zn 25.63, 7.69–168.1 (23.82, 8.82–109.2). The 85th percentile, calculated for station mean concentrations (μg/g wet weight) for 1978–1979 and 1980–1981, respectively, were: Pb 0.32 and 0.25; Hg 0.18 and 0.18; Cd 0.09 and 0.06; As 0.23 and 0.22; Se 0.70 and 0.71; Cu 1.14 and 0.90; and Zn 46.26 and 40.09. There was no significant upward or downward trend between collection periods of the national geometric means of any of the elements except for cooper which decreased significantly. Species differences in elemental concentrations contributed more variability to the data set than did station differences. The proportion of the collections composed of each species changed little between collection periods. Thus, the magnitude of the species effect on the national geometric mean of each period was probably fairly consistent; however, it precludes our making sound comparisons among various regions of the United States. As a participant in the National Contaminant Biomonitoring Program (NCBP), the U.S. Fish and Wild-life Service is responsible for monitoring temporal and geographic trends of organochlorine chemical and elemental contaminants in the nation's fresh-water fish, European starlings (Sturnus vulgaris), and waterfowl. Primary emphasis has been placed on organochlorine chemical contaminants; however, certain elements have been measured intermittently and additional elements have been added periodically since 1969. We summarize the concentrations of the seven elements—lead, mercury, cadmium, arsenic, selenium, copper, and zinc—measured in freshwater fish collected during 1978–1981. Data for earlier collections have appeared in other reports (Hendersonet al. 1972; May and McKinney 1981; Walshet al. 1977).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Archives of environmental contamination and toxicology 29 (1995), S. 455-461 
    ISSN: 1432-0703
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Notes: Abstract Survival of anuran embryos and tadpoles is reduced in acidic (pH〈5.0) waters under laboratory conditions. However, field data on the presence-absence of amphibian species and acidity are equivocal. This study attempts to reconcile some of this discrepancy by using macrocosms to examine the interaction of soil type and water acidification on free-ranging tadpole populations. Tadpoles were caught with activity traps in 24 aquatic macrocosms experimentally treated with H2SO4 and Al2(SO4)3 and lined with either comparatively high metal, low organic matter clay soils or lower metal, higher organic matter loams. Northern cricket frog (Acris crepitans) tadpole abundance was less in acidified macrocosms than in circumneutral ones (p〈0.05) and less in those with loam soils than in macrocosms with clay soils (p〈0.04). Gray treefrog (Hyla versicolor) abundance was affected by an interaction between soil and acidification (p〈0.07) in that treatment effects were only observed in macrocosms with clay soils (p〈0.01). No differences were observed among treatments for green frog (Rana clamitans) or southern leopard frog (R. utricularia) tadpoles. The study shows that soil type may interact with water conditions to affect amphibian populations in acidified waters.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2002-10-01
    Print ISSN: 0090-4341
    Electronic ISSN: 1432-0703
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Published by Springer
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  • 5
    Publication Date: 1985-05-01
    Print ISSN: 0090-4341
    Electronic ISSN: 1432-0703
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Published by Springer
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  • 6
    Publication Date: 2015-03-04
    Description: The use of quasicrystals as precursors to catalysts for the steam reforming of methanol is potentially one of the most important applications of these new materials. To develop application as a technology requires a detailed understanding of the microscopic behavior of the catalyst. Here, we report the effect of leaching treatments on the surface microstructure, chemical composition, and valence band of the icosahedral ( i -) Al-Cu-Fe quasicrystal in an attempt to prepare a model catalyst. The high symmetry fivefold surface of a single grain i -Al-Cu-Fe quasicrystal was leached with NaOH solution for varying times, and the resulting surface was characterized by x-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), scanning electron microscopy (SEM), and atomic force microscopy (AFM). The leaching treatments preferentially remove Al producing a capping layer consisting of Fe and Cu oxides. The subsurface layer contains elemental Fe and Cu in addition to the oxides. The quasicrystalline bulk structure beneath remains unchanged. The subsurface gradually becomes Fe 3 O 4 rich with increasing leaching time. The surface after leaching exhibits micron sized dodecahedral cavities due to preferential leaching along the fivefold axis. Nanoparticles of the transition metals and their oxides are precipitated on the surface after leaching. The size of the nanoparticles is estimated by high resolution transmission microscopy to be 5-20 nm, which is in agreement with the AFM results. Selected area electron diffraction (SAED) confirms the crystalline nature of the nanoparticles. SAED further reveals the formation of an interface between the high atomic density lattice planes of nanoparticles and the quasicrystal. These results provide an important insight into the preparation of model catalysts of nanoparticles for steam reforming of methanol.
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 7
    Publication Date: 1997-03-01
    Print ISSN: 0007-4861
    Electronic ISSN: 1432-0800
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Published by Springer
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