ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 308-318 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Previous publications have shown that the stress-strain behavior, especially ductility, of some incompatible polymer blends are greatly improved by the addition of slurry produced chlorinated polyethylenes (CPE). This improvement is greatest for blends containing polyethylene and PVC. The most effective CPE's have some residual polyethylene crystallinity and may be described as block-like polymers with ethylene sequences and chlorine containing sequences. It is postulated that CPE addition improves the blend properties by increasing the adhesion between domains in the blend via interactions with the blend components. This hypothesis was explored by thermal analysis, dynamic mechanical testing, adhesion studies, and microscopy. It is concluded that the interaction of CPE with polyethylene derives from compatibility of rather long methylene sequences in CPE with the polyethylene which results in good adhesive bonding. The interaction of CPE with PVC may not be owing to segmental compatibility but simply good mutual adhesion between similar polar materials. There is no interaction or adhesion between CPE and polystyrene as would be expected. CPE addition to blends is accompanied by a decrease in component domain size. The relationship between CPE structure and its effectiveness as a blend modifier is discussed.
    Additional Material: 22 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 12 (1972), S. 157-166 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Plastics in solid wastes is a problem of growing concern. Recycling of wastes is currently believed to be the most acceptable form of disposal in the long run; however, this route is known to be especially difficult for plastics. Recycling would be easier if the various generic types present in solid wastes, mainly polyethylene, polystyrene and poly (vinyl chloride), could be isolated; however, this would be very difficult and expensive. This is a first report on research aimed at evaluating the potential of recycling plastics as a polymer blend of the various generic types. This approach suffers from the difficulty that the different plastics are incompatible and the blend has poor mechanical properties. The extent of this problem is documented with data on many ternary blends employing virgin polyethylene, polystyrene and poly (vinyl chloride) of numerous grades likely to be found in solid wastes. Property degradation was found to be more severe as the complexity of the blend increased, indicating that general municipal wastes could be reused only in very low grade applications, whereas certain commercial wastes might have brighter prospects. Strategies for improving blend properties are outlined.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 13 (1973), S. 202-208 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Recycling of waste plastics as a blend of generic types is attractive since a difficult separations problem is avoided. However, blends of incompatible polymers are frequently very brittle and cannot be considered for many applications. Additives which modify the blend to give it ductility may provide a solution to this problem. Chlorinated polyethylene (CPE) made by a slurry process has been suggested for this application by Schramm and Blanchard. Further documentation of the effectiveness of this approach is given here. Addition of CPE to such a blend generally increases the elongation at break and the energy to break very dramatically with ordinarily some loss in strength and modulus. This approach works most effectively in blends of high polyethylene and poly(vinyl chloride) content. Three grades of CPE were studied here which revealed that the specific structure of the CPE molecule is a factor. The effectiveness of CPE for blend modification is believed to derive from the graded molecular structure acquired during chlorination.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 2791-2800 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The use of graft copolymers of styrene onto polyethylene as additives to improve the mechanical properties of polyethylene-polystyrene blends is described. Blends containing equal proportions of low-density polyethylene and polystyrene were selected for this study since this composition represents the poorest balance of properties in this system. Graft addition generally increased both the yield strength and the elongation at break of the blend. Of the grafts employed, those prepared at an irradiation dose near 0.5 megarad appear optimal for this purpose. These conditions apparently balance the beneficial effects of grafting extent and the detrimental effects of crosslinking, both of which increase with irradiation dose.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 17 (1973), S. 2597-2617 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The preparation and characterization of styrene-low-density polyethylene graft copolymers for addition to blends of polyethylene and polystyrene to improve blend mechanical properties is described. The direct method of grafting with 60Co radiation was employed using the polyethylene in pellet form. This approach gave good grafting efficiency with maximum yields limited to about 1 g of styrene reacted per gram of polyethylene. Excessive crosslinking at radiation doses beyond about 1 mrad was detrimental to the melt processibility of the graft. Crystallinity, dynamic mechanical properties, morphology, and stress-strain behavior of the grafts were examined and compared with melt blends of similar composition in order to better characterize the material produced.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...