Publication Date:
2015-06-25
Description:
The zinc(II) coordination polymers [Zn(Htatb)(2,2′-bipy) · (NMP) · H 2 O] ( 1 ) and [Zn 3 (tatb) 2 (2,2′-bipy) 3 · H 2 O] ( 2 ) (H 3 tatb = 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoic acid; 2,2′-bipy = 2,2′-bipyridyl, NMP = N-methyl-2-pyrrolidon), were synthesized hydrothermally, and characterized by infrared spectroscopy (IR), powder X-ray diffraction (PXRD), and single-crystal X-ray diffraction. Both compounds 1 and 2 possess expectant low dimensional coordination structures, which further connected into interesting 3D networks by hydrogen bond and strong π–π interactions. Moreover, the thermal stabilities and fluorescent properties of 1 and 2 were investigated.
Print ISSN:
0044-2313
Electronic ISSN:
1521-3749
Topics:
Chemistry and Pharmacology
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