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  • 1
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 5173-5175 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Crystal-structure studies on Tm2Fe17−xGax (x=0, 1, 2, 3, 4, 5, 6, 7, and 8) compounds have shown that the prepared samples are single phase with the 2:17-type structure. Both the unit-cell volume and the saturation magnetization at 1.5 K decrease linearly with increasing Ga content. The Curie temperature is found to increase with increasing x; it goes through a maximum value of 485 K at about x=3 to lower values and then it rises again. The Tm2Fe17−xGax compounds exhibit a spin–reorientaiton transition at low temperature. X-ray diffraction measurements on magnetically aligned Tm2Fe17−xGax powders show that the compounds with x≤6 have the easy-plane type of magnetic anisotropy, whereas the compounds with x[less, eq, greater]7 exhibit the easy c-axis type of magnetic anisotropy at room temperature. © 1997 American Institute of Physics.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 1385-1387 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The structure and magnetic properties of arc-melted Gd2Fe17−xGax compounds were studied by means of x-ray diffraction and magnetization measurements. X-ray diffraction patterns demonstrate that all samples have a rhombohedral Th2Zn17-type structure and the substitution of Ga leads to an approximately linear increase in the unit cell volumes. The Curie temperature is found to first increase and then decrease with increasing Ga concentration. It is noteworthy that the substitution of Ga has a significant effect on the magnetic anisotropy of iron sublattice. The easy magnetization direction of Gd2Fe17−xGax compounds changes from basal plane to c axis with increasing Ga concentration. The sample with x=7 exhibits a uniaxial anisotropy. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 2637-2640 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Iron-rich intermetallic compounds Sm2Fe17−xSix and Sm2Fe17−xSixC (x=0, 1, 2, and 3) were studied. The as-prepared compounds are single phase with the rhombohedral Th2Zn17-type structure except for Sm2Fe17C and Sm2Fe16SiC which contain some amounts of α-Fe. The unit cell volumes and saturation magnetization at room temperature are found to decrease linearly with increasing Si concentration x. The Curie temperature Tc is found first to increase and then to decrease with increasing Si content. X-ray diffraction measurements on magnetically aligned powder samples show that the easy magnetization direction of the Sm2Fe17−xSix samples with x≤2 is planar while that of the sample with x=3 is conical. The Sm2Fe17−xSixC samples with x≤3 exhibit an easy c-axis anisotropy at room temperature. The anisotropy field is 83 kOe for x=0 and it rises to 110 kOe at x=1, and then drops with increasing Si concentration to 55 kOe at x=3. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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  • 4
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The effects of the substitution of Co for Fe on the formation, structure, and magnetic properties of Sm2Fe14Ga3C2 compounds were studied. Alloys with composition Sm2(Fe1−xCox)14Ga3C2 (x=0, 0.1, 0.2, 0.3, 0.4, and 0.5) were prepared by arc melting. X-ray diffraction shows that these alloys are single phase compounds of the rhombohedral Th2Zn17-type structure. The lattice constants a and c, and the unit cell volumes v of Sm2(Fe1−xCox)14Ga3C2 compounds decrease monotonically with increasing cobalt concentration. It is found that the Curie temperature increases from 615 K for x=0 to 666 K for x=0.5. Room-temperature saturation magnetization is 90.3 emu/g for x=0, and it decreases to 79.6 emu/g at x=0.5. All compounds of Sm2(Fe1−xCox)14Ga3C2 studied in this work exhibit an easy c-axis anisotropy at room temperature. The anisotropy field is higher than 90 kOe for x≤0.2, and it decreases slightly with x≥0.3.
    Materialart: Digitale Medien
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  • 5
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Amorphous Nd2(Fe1−xCox)23B3 (0≤x≤1.0) alloys were prepared by melt spinning at a speed of 47 m/s. When the amorphous samples were annealed at 900 K for 20 min, they crystallized to the metastable 2:23:3 single phase for all x. A detailed study of structure and magnetic properties of metastable Nd2(Fe1−xCox)23B3 compounds has been made by x-ray diffraction and magnetization measurements. They are body-centered cubic, and the lattice constant decreases linearly from a=14.16 A(ring) for x=0 to 13.86 A(ring) for x=1.0. The Fe atom moment μ¯Fe for Nd2(Fe1−xCox)23B3 was found to increase with x from 2.02μB for x=0 to 2.17μB for x=0.8, when the Co atom moment μ¯Co is assumed to be constant, as made in previous papers for crystalline Fe–Co alloys. The Curie temperature Tc is found to increase monotonically with increasing x from 659 K for x=0 to about 1218 K for x=1.0. The thermomagnetic measurements showed that when the Nd2(Fe1−xCox)23B3 compounds were heated to certain temperatures, they decomposed to Nd2(Fe,Co)14B and α-(Fe,Co) phases. The decomposition temperature of metastable compounds was about 990±15 K, and was almost independent of the Co concentration x.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 5311-5313 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: X-ray diffraction (XRD) and magnetization measurements were employed to investigate the effect of Mn substitution for Co on the structure and magnetic properties of Y2Co17−xMnx compounds with x=0–8. XRD patterns show that all samples are single phase with a hexagonal Th2Ni17-type structure. The substitution of Mn for Co in Y2Co17−xMnx compounds leads to a monotonic increase in unit cell volume. The saturation magnetization remains nearly constant for x≤3, then decreases quickly with increasing Mn content; this can be explained by the change of the 3d energy band structure and an electron transfer process. The Curie temperature TC is found to decrease rapidly with increasing Mn concentrations. X-ray diffraction measurement on magnetically aligned Y2Co17−xMnx compounds exhibit an easy-plane type of magnetic anisotropy at room temperature for x=0 and an easy-axis type of magnetic anisotropy at room temperature with x=1–7. Substitution of Mn for Co leads to a change of the magnetocrystalline anisotropy of the Co sublattice from the basal plane to the c axis and strongly increases the uniaxial anisotropy of Y2Co17−xMnx. The magnetocrystalline anisotropy field HA is found first to increase and then decrease with increasing Mn concentration, attaining a maximum value of 20.6 kOe at x=3. © 2000 American Institute of Physics.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 4903-4905 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Samples of (Pr1−xCex)6Fe13Al (x=0.1, 0.2, 0.3, 0.4, 0.5, and 0.6) were prepared by arc melting and annealed for two weeks at 973 K. The x-ray diffraction patterns show that all the samples crystallize with the Nd6Fe13Si-type structure. The unit-cell volume increases first and then decreases as the Ce content increases. The Curie temperature and the spontaneous magnetization decrease almost linearly with increasing Ce concentration, supporting the existence of a mixed valence of Ce3+ and Ce4+. The series is ferromagnetic at high temperature; however, the peak at low temperature of the M–T curve most likely corresponds to spin-glass behavior. © 2000 American Institute of Physics.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 4666-4668 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: An investigation of the structure and magnetocrystalline anisotropy of Ce2Co17−xAlx (x=0, 1, 2, and 3) compounds has been performed by means of x-ray diffraction and magnetization measurements. It is observed that the unit-cell volume, Curie temperature, and saturation magnetization of Ce2Co17−xAlx compounds are anomalously low in comparison with the values obtained from a simple extrapolation by the other R2Co17−xAlx compounds, such as R=Pr and Nd. These anomalies may be an evidence of a mixed-valence behavior of the Ce ion. X-ray diffraction measurements on magnetically aligned Ce2Co17−xAlx powders with x=0–3 exhibit an easy-axis type of magnetic anisotropy at room temperature. Substitution of Al for Co leads to a change of the magnetocrystalline anisotropy of the Co sublattice from the basal plane to c axis and strongly increases the uniaxial anisotropy of Ce2Co17−xAlx. The magnetocrystalline anisotropy field HA is found first to increase and then decrease with increasing Al concentration, attaining a maximum value of 18 kOe at x=2. The magnetocrystalline anisotropy constant K1 shows a small decrease with increasing temperature and K2 is almost a constant. © 1999 American Institute of Physics.
    Materialart: Digitale Medien
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  • 9
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The effect of Ga substitution for Fe in R2Fe17 (R=Y, Sm, Gd, Tb, Dy, Ho, Er, and Tm) compounds on the structure and magnetocrystalline anisotropy has been studied by means of x-ray diffraction and magnetization measurements. Both iron sublattice anisotropy and rare earth sublattice anisotropy are found to be modified by the introduction of the gallium atoms. A uniaxial anisotropy is shown in R2Fe17−xGax (for R=Y, Gd, Tb, Dy, Ho, Er, and Tm) compounds with high Ga concentration, whereas a reversal change in the easy magnetization direction is observed in the samples for R=Sm. The contributions to the uniaxial orientation of the magnetization in these compounds result from not only the rare earth sublattice, but also the iron sublattice. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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  • 10
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The Rietveld analysis of x-ray diffraction data shows that Ho2Fe17−xGax (x=0–8) solid solutions crystallize with the Th2Ni17 structure for x≤2, the Th2Zn17 structure for x≥4, and the two coexisting phases for x=3. The unit-cell volume increases linearly with a slope of 8.7 Å3 per Ga atom. At lower gallium concentrations, Ga atoms occupy the 18f, 18h sites in the Th2Zn17 structure (or 12j, 12k sites in the Th2Ni17 structure) and avoid the 6c, 9d sites. For higher Ga content (x≥6) Ga atoms still avoid the 9d site, but preferentially occupy 6c and 18f sites for x=6–8 while the occupancy factor of the 18h site decreases. Gallium substitution decreases the saturation magnetization linearly with a slope of 2.5μB. The compounds Ho2Fe17−xGax (x=7,8) possess uniaxial magnetocrystalline anisotropy at room temperature. Doping first increases, then decreases the Curie temperature until this finally rebounds for x〉6. The "anomalous" enhancement of the Curie temperature for x=7, 8 may be correlated with the variation of the Fe–Fe bond lengths. © 1998 American Institute of Physics.
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