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  • 1
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 86 (2003), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Nanocrystalline ceramics are expected to possess enhanced superplasticity over their microcrystalline counterparts. In this effort of producing nanocomposites of silicon nitride and silicon carbide, amorphous Si-C-N derived from pyrolysis of a polysilazane precursor was sintered with yttria as an additive. High-pressure sintering at different temperatures resulted in sintered materials ranging from amorphous to nanocrystalline. High-resolution transmission electron microscopy was conducted to characterize the development and grain-boundary features of the nanocrystalline microstructure. The results provide a preliminary understanding of the process of the formation of the nanocrystalline structure from an amorphous matrix, under the condition of high pressure and relatively low temperature. The wide variation in the thickness of grain-boundary phases observed in this material suggests a nonequilibrium state of the grain boundary, which might be related to the processing conditions.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 110 (1992), S. 154-172 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Chemical interaction between tholeiitic magmas of the East Greenland Tertiary macrodike complex and anatectic melts of the Precambrian basement produced a wide range of hybrid magmas. Field evidence indicates that, although coexisting magmas were stirred, mechanical mixing only occurred to a limited extent before segregation of magmas into a stratified system. The initial 87Sr/86Sr and 143Nd/144Nd isotope ratios for hybrid compositions fall between those of the mafic and felsic end-members. However, the covariation of these isotope ratios differs from that expected of bulk mixing. Major- and trace-element distributions in hybrid magmas are also inconsistent with simple mixing, as well as with fractional crystallization coupled with bulk assimilation (AFC) involving reasonable end-members of the macrodike-crust system. Rather, the chemical and isotopic modification of mafic and felsic magmas of the macrodike complex appears to have been controlled fundamentally by interdiffusion of silicate liquid species during mingling and buoyant roofward segregation of crust-derived granophyres. The relationships among juxtaposed hybrid magmas of the Miki Fjord macrodike are shown to be consistent with expectations of selective diffusional exchange based on available experimental interdiffusion data for silicate liquids. Comparison between these hybrid compositions and rocks from the felsic series of the Vandfaldsdalen macrodike suggest that the latter compositions were affected by a similar opensystem process operating presumably during the transient development of the felsic cap. Once hybrid magmas ponded at the roof of the intrusion they effectively were isolated from further exchange.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 102 (1989), S. 492-513 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Crystal dissolution may include three component processes: interface reaction, diffusion and complications due to convection. We report here a theoretical and experimental study of crystal dissolution in silicate melt without convection. A reaction-diffusion equation is developed and numerically solved. The results show that during non-convective crystal dissolution in silicate melt, the interface melt composition reaches a constant or stationary “saturation” composition in less than a second, hence interface reaction is not the rate-determining step and crystal dissolution in silicate melt is usually diffusion-controlled. Crystal dissolution experiments (designed to suppress convection) show that the concentration profiles of all components propagate into the melt according to the square root of run duration, and that the dissolution distance is also proportional to the square root of run duration. Thus our experiments confirm that the dissolution is diffusion controlled, which is consistent with our numerical calculations. For some principal equilibrium-determining components, concentration profiles conform approximately to the analytical solution of the diffusion equation with a constant effective binary diffusion coefficient. Diffusive dissolution rates (which are inversely proportional to square root of time) can thus be predicted from the phase equilibria and the effective binary diffusion coefficients. To predict steady-state convective dissolution rates, the thickness of the boundary layer must be known. If the convective compositional boundary layer thickness around a dissolving crystal aggregate or near the wall of a magma chamber during convection is about 2 cm or larger, then convective dissolution would rarely result in any significant alteration of original melt. Our dissolution experiments also illustrate the complexity of the diffusion process. Uphill diffusion is common, especially during olivine dissolution into andesitic melt where a majority of the components show the effect of diffusion up their own concentration gradients. Uphill diffusion has implications to the understanding of crystal zoning, and suggests caution is required in applying least squares mass balance analysis to magmatic rocks affected by processes involving diffusion.
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  • 4
    Publication Date: 2024-01-09
    Keywords: 152-917A; 152-918D; 163-989B; Albite; Aluminium oxide; Anorthite; Apatite; Calcium oxide; Calculated; Chromite; CIPW Norm; Diopside; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Elements, total; Event label; Greenland Sea; Hypersthene; Ilmenite; Iron oxide, FeO; Joides Resolution; Leg152; Leg163; Loss on ignition; Magnesium number; Magnesium oxide; Manganese oxide; Method comment; Ocean Drilling Program; ODP; Olivine; Orthoclase; Phosphorus pentoxide; Piece; Potassium oxide; Sample code/label; Silicon dioxide; Sodium oxide; Titanium dioxide
    Type: Dataset
    Format: text/tab-separated-values, 116 data points
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  • 5
    Publication Date: 2024-01-09
    Keywords: 152-917A; 152-918D; 163-989B; Aluminium oxide; Aluminium oxide, standard deviation; Anorthite; Anorthite, standard deviation; Calcium oxide; Calcium oxide, standard deviation; CAMECA electron microprobe; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; EXP; Experiment; Greenland Sea; Iron oxide, FeO; Iron oxide, FeO, standard deviation; Joides Resolution; Leg152; Leg163; Magnesium oxide; Magnesium oxide, standard deviation; Number; Ocean Drilling Program; ODP; Piece; Potassium oxide; Potassium oxide, standard deviation; Run; Sample code/label; Silicon dioxide; Silicon dioxide, standard deviation; Sodium oxide; Sodium oxide, standard deviation; Temperature, technical; Titanium dioxide; Titanium dioxide, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 506 data points
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  • 6
    Publication Date: 2024-01-09
    Keywords: 152-917A; 152-918D; 163-989B; Aluminium oxide; Aluminium oxide, standard deviation; Calcium oxide; Calcium oxide, standard deviation; CAMECA electron microprobe; Chromium(III) oxide; Chromium(III) oxide, standard deviation; Distribution coefficient; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Enstatite; Event label; EXP; Experiment; Ferrosilite; Greenland Sea; Iron oxide, FeO; Iron oxide, FeO, standard deviation; Joides Resolution; Leg152; Leg163; Magnesium number; Magnesium number, standard deviation; Magnesium oxide; Magnesium oxide, standard deviation; Manganese oxide; Manganese oxide, standard deviation; Number; Ocean Drilling Program; ODP; Piece; Run; Sample code/label; Silicon dioxide; Silicon dioxide, standard deviation; Sodium oxide; Sodium oxide, standard deviation; Temperature, technical; Titanium dioxide; Titanium dioxide, standard deviation; Wollastonite
    Type: Dataset
    Format: text/tab-separated-values, 621 data points
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  • 7
    Publication Date: 2024-01-09
    Keywords: 152-917A; 152-918D; 163-989B; Aluminium oxide; Aluminium oxide, standard deviation; Calcium oxide; Calcium oxide, standard deviation; Calculated; CAMECA electron microprobe; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; EXP; Experiment; Greenland Sea; Iron oxide, FeO; Iron oxide, FeO, standard deviation; Joides Resolution; Leg152; Leg163; Magnesium number; Magnesium oxide; Magnesium oxide, standard deviation; Manganese oxide; Manganese oxide, standard deviation; Number; Ocean Drilling Program; ODP; Phosphorus pentoxide; Phosphorus pentoxide, standard deviation; Piece; Potassium oxide; Potassium oxide, standard deviation; Run; Sample code/label; Silicon dioxide; Silicon dioxide, standard deviation; Sodium oxide; Sodium oxide, standard deviation; Temperature, technical; Titanium dioxide; Titanium dioxide, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 729 data points
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  • 8
    Publication Date: 2024-01-09
    Keywords: 152-917A; 152-918D; 163-989B; Calcium oxide; Calcium oxide, standard deviation; Calculated; CAMECA electron microprobe; Distribution coefficient; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Event label; EXP; Experiment; Forsterite; Forsterite, standard deviation; Greenland Sea; Iron oxide, FeO; Iron oxide, FeO, standard deviation; Joides Resolution; Leg152; Leg163; Magnesium oxide; Magnesium oxide, standard deviation; Manganese oxide; Manganese oxide, standard deviation; Nickel oxide; Nickel oxide, standard deviation; Number; Ocean Drilling Program; ODP; Piece; Run; Sample code/label; Silicon dioxide; Silicon dioxide, standard deviation; Temperature, technical
    Type: Dataset
    Format: text/tab-separated-values, 460 data points
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  • 9
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    Unknown
    PANGAEA
    In:  Supplement to: Lesher, Charles E; Cashman, Katharine V; Mayfield, J D (1999): Kinetic controls on crystallization of Tertiary North Atlantic basalt and implications for the emplacement and cooling history of lava at Site 989, Southeast Greenland rifted margin. In: Larsen, HC; Duncan, RA; Allan, JF; Brooks, K (eds.) Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 163, 1-14, https://doi.org/10.2973/odp.proc.sr.163.115.1999
    Publication Date: 2024-01-09
    Description: Equilibrium melting and controlled cooling experiments were undertaken to constrain the crystallization and cooling histories of tholeiitic basalts recovered by the Ocean Drilling Program drilling of Site 989 on the Southeast Greenland continental margin. Isothermal experiments conducted at 1 atm. and at the fayalite-magnetite-quartz buffer using lava sample Section 163-989B-10R-7 yielded the equilibrium appearance sequence with decreasing temperature: olivine at 1184 ± 2ºC; plagioclase at 1177ºC ± 5ºC; augite at 1167 ± 5ºC; and pigeonite at 1113 ± 12ºC. In controlled cooling experiments using the same starting composition and cooling rates between 10ºC/hr and 2000ºC/hr, we find a significant temperature delay in the crystallization of olivine, plagioclase, and augite (relative to the equilibrium appearance temperature); pigeonite does not form under any dynamic crystallization conditions. Olivine exhibits the largest suppression in appearance temperature (e.g., 30º for 10ºC/hr and 〉190º at 100ºC/hr), while plagioclase shows the smallest (~10ºC at 10ºC/hr; 30ºC at 100ºC/hr, and ~80ºC at 1000ºC/hr). These results are in marked contrast to those obtained on lunar basalts, which generally show a large suppression of plagioclase crystallization and modest suppression of olivine crystallization with an increased cooling rate. The results we report agree well with the petrography of lavas recovered from Site 989. Furthermore, the textural analysis of run products, representing a large range of cooling rates and quench temperatures (1150ºC to 1000ºC), provide a framework for evaluating cooling conditions necessary for glass formation, rates of plagioclase growth, and kinetic factors governing plagioclase growth morphology. Specifically, we use these insights to interpret the textural and mineralogical features of the unusual compound flow recovered at Site 989. We concluded from the analysis that this flow most likely records multiple breakouts from a distal tube at an abrupt break in slope, possibly a fault scarp, resulting in the formation of a lava fan delta. This interpretation implies that normal faulting of the oldest lava sequences (lower and, possibly, middle series) preceded eruption of Site 989 lavas.
    Keywords: 163-989B; Augite; Cooling rate; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; EXP; Experiment; Greenland Sea; Joides Resolution; Leg163; Mineral assemblage; Ocean Drilling Program; ODP; Olivine; Plagioclase; Run Number; Sample code/label; Temperature, technical; Time in minutes; Volcanic glass
    Type: Dataset
    Format: text/tab-separated-values, 253 data points
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  • 10
    Publication Date: 2024-01-09
    Keywords: 152-917A; 152-918D; 163-989B; Augite; DRILL; Drilling/drill rig; DSDP/ODP/IODP sample designation; Duration; Event label; EXP; Experiment; Greenland Sea; Joides Resolution; Leg152; Leg163; Mineral assemblage; Ocean Drilling Program; ODP; Olivine; Parameter; Piece; Plagioclase; Pyroxene; Run; Sample code/label; Temperature, technical; Volcanic glass; Weight loss
    Type: Dataset
    Format: text/tab-separated-values, 330 data points
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