ISSN:
1572-8943
Keywords:
modulated DSC
;
physical aging
;
standard DSC
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The physical aging characteristics of maltose glasses aged at two temperatures below the glass transition temperature, Tg, (Tg-10°C and Tg-20°C) from 5 to 10 000 min were measured by standard differential scanning calorimetry (SDSC) and modulated differential scanning calorimetry (MDSC). The experimentally measured instrumental Tg, the calculated Tg, and the excess enthalpy values were obtained for aged glasses using both DSC methods. The development of excess enthalpy as a function of aging time, as measured by both SDSC and MDSC, was fit using the Cowie and Ferguson and Tool-Narayanswamy-Moynihan models. The change in the Tg values and the development of the excess enthalpy resulting from physical aging measured by the two DSC methods are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010102421270
Permalink