ISSN:
0009-2940
Keywords:
Binuclear complexes
;
Zirconium
;
Group VI metals
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Heterometallic Binuclear Complexes, I. - Reactive Zr(IV)-M(0) Compounds (M = Cr, Mo, W) with Bridging Diphenylphosphinocyclopentadienide LigandsReaction of ZrCl2(C5H4PPh2)2 (1) with labile complexes M(CO)3L3 (M = Cr, L = acetonitrile, M = Mo, W, L3 = cycloheptatriene) gives the binuclear compounds ZrCl(μ-Cl)(μ-C5H4PPh2)2M(CO)3 [M = Cr (2), Mo (3), W (4)]. The Cl bridge is readily cleaved by ligands such as CO, MeCN, or P(OMe)3.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19891220820
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