ISSN:
1572-8862
Keywords:
Structure
;
copper-sulfur
;
cluster
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The cluster [Cu4(S5)2(C5H5N)4]·S8 with cage structure has been obtained by reaction of copper powder with sulfur and K2S x in pyridine, and its structure was determined by X-ray crystallography. The crystal data for the title compound: triclinic, P $$\bar 1$$ (No. 2),Z = 2,a = 11.818(4) Å,b = 13.155(3) Å,c = 14.177(4) Å, α = 93.79(2)°,β = 96.68(2)°, γ = 115.76(2)°,V = 1954.52(1) Å3. The structure was refined toR = 0.038R w = 0.053) for 6444 data withI 〉 3.0σ(I).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01165469
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