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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Reaction kinetics and catalysis letters 22 (1983), S. 29-33 
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Исследована активность цеолитов У, обмененных на железо, в реакции превращения этилбензола. В присутствии воздуха, вначале, FeNaY обнаруживает высокую активность в деалкилировании этилбензола до бензола и толуола. Частичным обжигом катлизатора удалось достигнуть блокирования кислых центров, вызывающих деалкилирование, и тем самым достигнуть более высокого выхода стирола. Увеличение температуры активации и реакции до 550°C повышает конверсию и селективность к стиролу.
    Notes: Abstract The activity of ferric exchanged Y zeolite for the dehydrogenation of ethylbenzene is reported. In the presence of air, initially FeNaY showed high activity for dealkylation of ethylbenzene to benzene and toluene. With partial coking of the catalyst, some of the acidic centers responsible for dealkylation were blocked and higher conversion to styrene was achieved. Upon increasing the activation and reaction temperature to 550°C, the conversion and selectivity to styrene increased.
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  • 2
  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 6274-6278 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The wet chemical treatment using SeS2 is an inexpensive and simple method of depositing selenium on GaAs surfaces. This treatment improves the electronic properties of the surface as seen from the increase in photoluminescence intensity. We present our results on surface structural investigations of GaAs(110) surface passivated by SeS2 treatment using atomic force microscopy. Our results show that SeS2 treatment can passivate the GaAs(110) surface forming ordered overlayers on it. © 1996 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 1252-1260 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The large magnetic-field-dependent ac absorption in superconducting Y1 Ba2 Cu3 Oy ceramics and powders decreases slowly with increasing frequency in the range 2–16 MHz. The magnetic-field-dependent ac absorption is observed below Tc in superconducting Y1 Ba2 Cu3 Oy ceramics, powders and twinned crystals and in (La,Sr)2 CuO4 and BaPb0.75 Bi 0.25 CuO3 powders and appears to contain distinct contributions from trapped flux and/or intragrain tunnel junctions and from ordinary superconductor surface impedance. The contribution from trapped flux and/or intragrain tunnel junctions is important in dc magnetic fields of up to approximately 20 G at all temperatures below Tc. There is an identifiable modulated ac absorption which changes slowly over more than 12 kG at low temperatures and which we propose is primarily caused by the ac surface impedance with possible contributions from the critical state. A twinned crystal of Y1 Ba2 Cu3 Oy exhibits the same ac absorption except that it has an anisotropic dependence on the applied dc magnetic field.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 2693-2698 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new electroplating technique for growing cadmium telluride films in a nonaqueous medium is reported. The influence of the deposition conditions on the structure, stoichiometry, and surface topography of the CdTe films has been discussed in light of the x-ray diffraction analysis, x-ray photoelectron spectroscopy, and scanning electron microscopy studies. Higher bath temperatures have been found to favor larger grain growth with a certain amount of orientation. The CdTe formation is not favored at temperatures 〈130 °C. The compositional analysis using x-ray photoelectron spectroscopy indicated that the films deposited under galvanostatic conditions are generally richer in cadmium. Nearly stoichiometric films can be deposited under potentiostatic conditions at a deposition potential of −0.8 V (with respect to Pt neutral electrodes). A uniform and regular growth of CdTe films with no sign of cracking was also observed in the surface investigations by a scanning electron microscope.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 65 (1989), S. 2142-2144 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: High-Tc superconducting tubes have been developed for magnetic shielding of SQUIDs at 77 K. The characteristics of such tubes show that adequate shielding exists for magnetic fields up to a critical field determined by the current density of the tube. Relaxation phenomena with two different time dependencies are observed when the external magnetic field enters the tubes.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 72 (2001), S. 1869-1875 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The lower hybrid current drive (LHCD) system is an important system in superconducting steady state tokamak (SST-1). It is used to drive and maintain the plasma current for 1000 s with a duty cycle of 17%. The LHCD system is being designed to launch 1 MW of radio frequency (rf) power at 3.7 GHz. The rf source is comprised of two high power klystron amplifiers, each capable of delivering 500 kW rf power. In this article, the results obtained during installation and commissioning of these klystrons are presented. Two klystrons (model TH2103D) have been successfully installed and commissioned on dummy loads, delivering ∼200 kW power for more than 1000 s. The maximum output power that could be obtained is limited due to the available direct current (dc) power supply. The test system is comprised of a TH2103D klystron, a low power rf (3.7 GHz/25 W) source, two high power four port circulators, two high power dual directional couplers, two arc detector systems, and two dummy water loads. To avoid rf breakdown in the rf components of the transmission line, the system has been pressurized with dry air to 3 bar. To energize and operate the klystron, a high voltage dc power supply, a magnet power supply, an ion pump power supply, a −65 kV floating anode modulator power supply, and a filament power supply are used. An arc detector unit has been installed to detect and initiate action within a few microseconds to protect the klystron, waveguides, and other rf passive components during arcing. To protect the klystron in the event of an arc, a fast responding (〈10 μs), rail gap based pressurized crowbar unit has been used. The entire system is water cooled to avoid excess temperature rise during high power continuous wave operation of the klystron and other rf components. The tube requires initial conditioning. Thereafter, the output rf power is studied as a function of beam parameters such as cathode voltage and beam current. © 2001 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 2783-2788 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: X-ray and ultraviolet photoelectron spectroscopies were used to investigate the microscopic changes at the Ti/Bi2Sr2CaCu2O8 interface. Ti extracts oxygen out of the superconductor by disrupting vital bonds such as Cu—O and Bi—O. The adatom-induced oxygen withdrawal is explained on the basis of cationic bond lengths in the superconductor and standard bond strengths. The changes associated with Cu 2p spectra are attributed to an increase in covalency of Cu—O bonds, which is the consequence of a rearrangement of oxygen anions around Cu+2 ions. In the early stages of the interface formation, bismuth and titanium are in a complex bonding configuration, which is evident from their binding energies. The line shape analysis of Ti 2p spectra reveals that Ti is in multiple oxidation states at different stages of the evolving interface. This shows that the mobility of oxygen is an important factor which controls the overlayer growth.
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 2702-2704 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Free-standing powder of zinc sulphide quantum particles has been synthesized using a chemical route. X-ray diffraction analysis shows that the diameter of the particles is ∼21±2 A(ring) which is smaller than the Bohr exciton diameter for zinc sulphide. UV absorption shows an excitonic peak centered at ∼300 nm corresponding to an energy gap of 4.1±0.1 eV. These particles show a luminescence band at ∼424 nm. The quantum particles could be doped with copper during synthesis without altering the UV absorption or x-ray diffraction pattern. However, doping shifted the luminescence to 480 nm, green wavelength in the visible region. © 1995 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 2506-2508 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Zinc sulphide nanoparticles in the size range ∼10–40 A(ring) diameter have been synthesized using the aqueous chemical method. Scanning tunneling microscopy showed that particles are indeed nanosize particles. The size dependent band gap could be varied from a bulk value of 3.68 to 4.5 eV. X-ray diffraction indicated that nanoparticles are crystalline except for those with band gap ∼4.5±0.1 eV. Nanoparticles with particle size ∼21×2 A(ring) diameter or energy gap 4.1×0.1 eV were doped with manganese. The photoluminescence peak at ∼600 nm corresponding to yellow light emission was observed. Atomic absorption studies show that maximum luminescence intensity is achievable with 0.12 at. wt % of Mn doping. © 1995 American Institute of Physics.
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