Publication Date:
2015-12-17
Description:
Non-stoichiometric monoclinic 4C pyrrhotite (Fe 7 S 8 ) is a major magnetic remanence carrier in the Earth's crust and in extraterrestrial materials. Because of its low-temperature magnetic transition around 30 K also known as Besnus transition, which is considered to be an intrinsic property, this mineral phase is easily detectable in natural samples. Although the physical properties of pyrrhotite have intensively been studied, the mechanism behind the pronounced change in magnetization at the low-temperature transition is still debated. Here we report magnetization experiments on a pyrrhotite crystal (Fe 6.6 S 8 ) that consists of a 4C and an incommensurate 5C* superstructure that are different in their defect structure. The occurrence of two superstructures is magnetically confirmed by symmetric inflection points in hysteresis measurements above the transition at about 30 K. The disappearance of the inflection points and the associated change of the hysteresis parameters indicate that the two superstructures become strongly coupled to form a unitary magnetic anisotropy system at the transition. From this it follows that the Besnus transition in monoclinic pyrrhotite is an extrinsic magnetic phenomenon with respect to the 4C superstructure and therefore the physics behind it is in fact different from that of the well-known Verwey transition.
Keywords:
Geomagnetism, Rock Magnetism and Palaeomagnetism
Print ISSN:
0956-540X
Electronic ISSN:
1365-246X
Topics:
Geosciences
Published by
Oxford University Press
on behalf of
The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
