ISSN:
1434-1948
Keywords:
Silicon
;
Silyl anions
;
Lithium
;
Silanes
;
Polysilyl dianions
;
α,ω-Dilithiooligosilanes
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(Me3Si)3Si(Me2Si)2(Me3Si)2SiLi (1) and LiSi(Me3Si)2(Me2Si)2Si(Me3Si)2Li (2) were synthesized by the reaction of (Me3Si)3Si(Me2Si)2Si(Me3Si)3 in THF with one or two mol-equivalents, respectively, of MeLi. Both 1 and 2 were characterized spectroscopically and by trapping reactions, and 1 also by X-ray crystallography.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
Permalink