ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
In order to prepare aldehydocelluloses which are more stable than periodate-oxidized cellulose, completely allylated methylcellulose, allylated ethylcellulose, and tri-O-allylcellulose were subjected to ozonization followed by reduction with dimethylsulfide. The aldehydocelluloses thus prepared without any degradation showed the presence of many free aldehyde groups by IR and 13C-NMR spectrometries, as well as the presence of hydroxyl groups which were produced by deallylation. The degree of substitution (DS) by aldehyde group was 0.6 for the products from both completely allylated methylcellulose and tri-O-allylcellulose, and 0.02 for that from allylated ethylcellulose.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1988.070350404
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