ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Cyclohexenyl cations that are long-lived at −50°C are stabilized by the GeCl3 − anion and are detected and characterized spectrally in reactions of HGeCl3 with 1,3-dialkoxybenzenes. Further reactions of the cyclohexenyl cations are studied. The x-ray crystal and molecular structure of the final reaction product of HGeCl3 with 1,3-diethoxybenzene — 1,1,3,5-tetrakis(trichlorogermyl)-3-ethoxycyclohexane — is solved.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00960350
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