ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary 1. A study was made of the kinetics of the isomerization of the individual Δ − 1,4 , Δ − 2,4a(8a) , and Δ1(8a),4 hexalin-1,2-dicarboxylic acids, and their mutual transformations are shown schematically. 2. The Δ2,4a(8a)-isomer may be formed in the reaction mixture both directly from the Δ 1,4-acid as the result of a one-stage reaction and also from the conjugated Δ1(8a,4-acid. 3. The Δ1(8a),4-acid is not stable under the isomerization conditions, and it is readily converted into 5,6,7,8-tetrahydro-1, 2-naphthalenedicarboxylic acid.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00846961
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