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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Entomologia experimentalis et applicata 84 (1997), S. 127-135 
    ISSN: 1570-7458
    Keywords: Hemiptera ; Heteroptera ; Lygaeidae ; Oncopeltus ; Tropidothorax ; Neacoryphus ; pheromone ; attractant ; aposematic ; Asclepiadaceae
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract (E)-2,7-Octadienyl acetate and (E) -2-octenyl acetate (1:10 by volume) were identified as a pheromone attractive to both sexes of the lygaeid bug, Tropidothorax cruciger. In a parallel investigation of Neacoryphus bicrucis (Lygaeidae), (E, E) -2,4-hexadienyl acetate and phenethyl acetate (≈9:1) were identified from males, and found attractive to both sexes of adults in the field plus a tachinid fly parasitoid of the bugs. In N. bicrucis, the pheromone was clearly shown to come from the tubular accessory glands of the metathoracic scent gland; this evidence, plus earlier literature reports for other species, indicate that male lygaeids are the pheromone emitters. In another lygaeid, Oncopeltus fasciatus, 2-isobutyl-3-methoxypyrazine was identified in the cardiac glycoside-laden fluid sequestered from milkweed hosts and expelled by these bugs when they are attacked. Alkyl methoxypyrazines are warning odorants associated with poisonous insect secretions, and their presence in O. fasciatus indicates that the plant-derived chemical defense of lygaeines is more elaborate than previously appreciated.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-1561
    Keywords: Oriental fruit fly ; Dacus dorsalis Hendel ; Diptera ; Tephritidae ; methyl eugenoi analogs ; synthesis ; coupling reaction ; benzylic bromides ; attractants ; lures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract A general synthetic approach to various catechol derivatives was developed using a copper-catalyzed cross-coupling reaction of 1,2-dimethoxy-4-brornomethyl, 1-ethoxy-2-methoxy-4-bromomethyl- and 2-ethoxy-1-methoxy-4-bromomethylbenzenes with Grignard reagents. Dilithium tetrachlorocuprate was an acceptable catalyst in the dimethoxy series, whereas copper(I) iodide in THF-HMPA was a superior catalyst in all cases due to decreased side reactions, i.e., reduction and reductive coupling. Methyl-substituted analogs of methyl eugenol, a potent attractant of Oriental fruit fly,Dacus dorsalis Hendel, were synthesized by this method and evaluated for attractancy in field tests.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0749-1581
    Keywords: Penta-1,3-dien-5-ols ; 1H{1H} NOE ; 2D J-resolved 13C NMR ; 1H, 1H allylic coupling ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Established NMR criteria from 1H, 13C and 2D J-resolved 13C NMR spectra, and also 1H{1H} NOE experiments, were used to determine the constitution and configuration in a series of substituted penta-1,3-dien-5-ols.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
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