ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary The polymerization of methyl methacrylate (MMA), ethyl acrylate (EA), styrene (St) and 2-vinyl pyridine (VP) is initiated upon irradiation at λ〉350 nm of dichloromethane solutions containing N-ethoxy-2-methylpyridinium hexafluorophosphate (EMP+PF6 -) and anthracene or thioxanthone. Initiation mechanisms involving the formation of ethoxyl radicals during the decomposition of EMP+ ions via electron transfer are proposed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00973906
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