ISSN:
1573-9171
Keywords:
13C NMR spectra
;
17-ethynylandrostenes
;
Co-complexes
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract 13C NMR spectra of epimeric 17α-R-substituted 17β-ethynylandrostenes (R = H, OH, OAc, OMe, NCS) and 17β-R-substituted 17α-ethynylandrostenes (R = H, OH, OAc, OMe), and their hexacarbonyldicobalt complexes, as well as of Δ16-17-ethynylandrostenes and their hexacarbonyldicobalt complexes have been studied. Stereochemical dependence of C(12), C(14), C(18), C(20) and C(21) chemical shifts on the configuration of the substituents at C(17) has been demonstrated. The effect of Co-complexation on the spectral characteristics of Co-coordinated 17-ethynylandrostenes in both Stereochemical series has been investigated.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00700008
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