ALBERT

Description: In field experiments conducted on a poorly drained clay loam soil from 1974 to 1976, inclusive, 21–44% of added chloride was lost from the 0- to 75-cm layer by the end of September, whereas NO3−-N increased in this layer in both the control and fertilized plots. Mineralization during the summer masked any N losses by leaching or denitrification. N losses were highest between late fall and early spring. NO3−-N and chloride tended to show similar distribution patterns in the profile but not necessarily similar leaching losses, since simultaneous denitrification occurred in an adjacent experimental site. Chloride distribution in the profile and leaching losses did not appear to coincide with expectations of typical transport theory, since losses were associated with diffuse bulges near the surface instead of distinct peaks or slugs of chloride moving steadily downward.

Description: The mineralization of soil sulfur, as measured by calcium chloride extraction of fresh samples, was compared and discussed with carbon-dioxide-evolved, nitrogen mineralized, sodium-bicarbonate-extractable phosphate, lipid phosphorus and arysulfatase activity. The amount of sulfur mineralized after 14 wk was compared with various initial soil values, such as the form of sulfur and ratios among C, N and S. In general, the samples with larger C:S and C:N ratios resulted in lower sulfur- and nitrogen-mineralizable values; however a complex interrelationship among C, N and S was evident. A high N:S ratio (produced by addition of nitrogen) resulted in a decrease in mineralization of sulfur in the soil sample during an 8-wk incubation.

Description: Nitrogen in fallow soil in four field trials was monitored at Agassiz to examine the response of N processes under humid weather conditions of south coastal British Columbia. Inorganic N in the soil profile of control and ammonium-nitrate-treated plots were compared at various time intervals. In two trials (Spring-78 and Spring-81) treatments were applied in late May and in two (Fall-79 and Fall-82) in early November. Leaching of spring-applied N was quite limited during the spring and summer. In the Spring-78 trial, there was negligible nitrate movement until September whereas in the Spring-81 trial there was some movement in June. In the Spring-81 trial, upward movement of nitrate was detected in late August. Nitrate leaching in the summer of 1981 was associated with an unusually high amount of precipitation during June. Leaching of nitrate was significant in late October to December. Nitrogen applied in early November showed extensive leaching by late December. The ammonium appeared to have been nitrified quickly to enable leaching of the applied N as nitrate. Leaching of nitrate appeared to be associated with net water surpluses (precipitation less pan evaporation). Clay fixation of applied ammonium was detected immediately after fertilizer application in the fall but not in the spring trials. The applied ammonium that was fixed by clay was apparently released during the monitoring period. An increase of surface acidity due to ammonium nitrate application was detected in the Fall-79 trial. Comparison of nitrate leaching with long-term precipitation and pan-evaporation records shows that there is low risk of nitrate leaching during the spring and summer but high risk during the fall and winter in south coastal British Columbia. It was concluded that residual inorganic N after the growing season would not be available for crop growth in the spring due to nitrification and leaching over the winter. Development of a soil test for N would have to concentrate on the potential of the soil to mineralize soil N in the spring and early summer. Key words: Nitrogen leaching, nitrogen transformations, clay fixed NH4+, nitrification, fall nitrogen application

Description: The possibility of nitrate adsorption in 18 samples representing 11 soil types from the lower Fraser Valley of British Columbia was examined by differential extraction, equilibration and column leaching methods. Contrary to what was expected if nitrate was adsorbed by the soil, more nitrate was extracted by water than by 2 M KCl from some of the samples. Observations in related studies of greater microbial growth in 0.1 and 1.0 than in 2.0 M KCl extracts after more than 1 wk of storage and of different equilibrium results when conducted with and without toluene supported the conclusion that microbial or enzyme activity caused the larger amount of nitrate to be extracted by water than by 2 M KCl. Both equilibration and column leaching methods measured adsorption in some of the soil samples, but the amounts in the various samples by the two methods were not always the same. The equilibration method was analytically more precise than the column leaching method because it was simpler and required fewer measurements, but the column leaching method was considered to match more closely the soil to water ratio that would occur in the field. The equilibrium method found from 0 to 34% adsorption of the nitrate when added at a concentration not exceeding 50 μg N g−1. Further work is required to develop a practical method to meaningfully quantify nitrate adsorption in soils. The presence of nitrate adsorption has important implications for the interpretation of soil nitrogen research data and should possibly be included in nitrogen simulation models. The observation of microbial or enzyme effects on extraction of nitrate from soil shows the importance of using extraction solutions (e.g., those of high salt concentration or that contain a microbial inhibitor) that eliminate that possibility. Key words: Nitrate reactions, anion adsorption, nitrogen process, microbial effect, microbial inhibition

Description: The dynamics of fixation and release of NH4+ in soils were studied using tracer N under field and laboratory conditions. Field data showed that release of fixed NH4+ was relatively slow after an initial moderately fast release. Forty months of field weathering of Bainsville soil left 3.48 kg 15N/ha in the 75-cm profile of the 13.5 kg 15N/ha applied and most (76%) of this recovered 15N was fixed NH4+–N. The relative quantitative importance of recently fixed NH4+ in the various particle size fractions was not in the same order as the native fixed NH4+. The fine silt fraction (2–5 μm) fixed a larger amount (whole soil basis) than the fine clay fraction (

Description: A field experiment with an Ottawa area clay loam soil utilizing open-ended microplots and 15N-labelled fertilizer showed the relative importance of seasons on transformation and transport of nitrogen. Denitrification appeared to be appreciable during the growing season; about 39% of the fertilizer N was denitrified in 86 days (May–Sept.) and 65% was lost after 511 days but leaching losses were included in the latter period. Nitrification of fertilizer N was very rapid with extractable NH4+-N approximating background level within the first 43 days. Immobilization of fertilizer N was negligible in the first 159 days and only a small amount was immobilized during the remainder of the experiment. Mineralization of soil N averaged 0.77 and 1.10 kg N/ha/day in the first two sampling periods. Clay fixation of NH4+-N was significant in this soil with 59% of the 152 kg N/ha applied being immediately fixed. Over one-half (66%) of this recently fixed NH4+-N was released in the first 86 days of the experiment with the remainder held tightly through the sampling period. Movement of fertilizer N was greatest in the late fall and early spring, i.e. periods of high precipitation and low evaporation.

Description: A tracer (15N) study using fallowed field microplots was conducted at Agassiz Research Station to examine the fate of applied N over an entire year. The tracer confirmed nontracer (difference between fertilized and control treatments) observations that applied N does not leach beyond the rooting zone (45 cm) during the growing season, despite the considerably more than average precipitation that occurred in July, but that all residual [Formula: see text] is leached over the winter. The tracer did, however, show that net immobilization of applied N occurred late in the fall resulting in 17% of the N recovered in the 75-cm profile 1 yr after application even though the nontracer method showed that none of the applied N remained. There was significant net mineralization of soil N over the summer (100 kg N ha−1 from early May to late August) and nitrification of the applied [Formula: see text] (120 kg ha−1) was essentially complete within 14 d of application. Tracer analyses suggested that 36% of the applied [Formula: see text] was immediately fixed by the clays but after 14 d in the field it decreased to less than 1%. The fixed [Formula: see text] remained at this level throughout the rest of the year. The apparent large decrease in fixed [Formula: see text] within the first 14 d may have been an analytical artifact which resulted when the initial soil was air dried. Negligible denitrification was observed during the growing season despite the soil remaining quite moist throughout most of the year. Delta 15N measurements of total N, fixed [Formula: see text] and extractable inorganic N fractions showed only enrichment of total N. The delta 15N results support the observation that denitrification tends to be low under Agassiz soil and weather conditions. Comparisons and contrasts to previously reported similar tracer studies in Ottawa were made. Key words: Leaching, clay fixation, N mineralization, N immobilization, nitrification, denitrification, delta 15N

Description: Fertilizer is commonly applied as a band in red raspberry (Rubus idaeus L.) fields, resulting in complex spatial and temporal variation in soil inorganic N concentration, and in soil test P and K. The objectives of this study were to determine the spatial and temporal distribution of soil inorganic N in red raspberry fields receiving different N fertility treatments, to use the data to determine the most appropriate sampling strategies for estimating the quantity of soil inorganic N at various times during the growing season, and to evaluate the same sampling strategies for soil test P and K. Treatments were a control that received no manure or fertilizer N, 55 kg N ha-1 as urea or as Duration T60, a slow release N fertilizer, banded in mid-April, or 100 kg total N ha-1 as solid broiler manure broadcast or banded in early March, or banded in mid-April. Soil inorganic N was sampled at 10 inter-row locations 8, 23, 38, 53, 68, 83, 98, 113, 128, and 143 cm from the crop row, and for 0–15, 15–30, and 30–60 cm depth, for four sampling dates for the control and urea treatments, and for 0–15 and 15–30 cm depth on one sampling date for the remaining treatments. Random sampling and four systematic sampling strategies were evaluated for their bias in estimating soil inorganic N concentration and soil test P and K, and with respect to the number of soil cores required to achieve a given precision and probability level combination. The random sampling strategy gave unbiased estimates of soil inorganic N and soil test P and K, however, the number of cores required to obtain a given precision at a given probability level were generally greater than for the systematic sampling strategies. The systematic sampling strategy involving sampling only in the crop row and in the centre of the inter-row, the current industry standard, gave expected values that could sometimes be substantially lower than the true value, and was therefore not recommended for use in raspberry fields. The best systematic sampling strategy used samples collected from the crop row, from the fertilizer band, from the centre of the inter-row, and from midway between the fertilizer band and the centre of the inter-row. Key words: Rubus idaeus, nitrate leaching, nitrification, nitrate, ammonium

Description: Three years of field experiments showed the interplay of plant uptake of N, N movement, denitrification, fixation of fertilizer NH4+ and its release, and N mineralization in soil–plant systems. The N uptake by barley (Hordeum vulgare L.), averaged over the growing season, ranged between 0.97 and 2.02 kg N/ha/day and the rate depended on initial extractable inorganic N in the soil, and form and timing of N fertilization. The net mineralization rate of this soil, averaged over the growing season, ranged between 0.16 and 1.80 kg N/ha/day and varied with year and N fertilization practices. However, detailed monitoring of plant uptake showed that a maximum rate of uptake occurred early in its growth, decreasing to a negligible rate later in the season. The N mineralization rate was more uniform over the growing season. A pool of inorganic N in the soil at seeding or within the first half of the growing season overcame the seasonal deficit in N supply and resulted in increased crop growth and/or N uptake. Fertilizer N movement was small and never beyond the maximum (75-cm) sampling depth. This supported the assumption that unrecovered fertilizer N in this study was largely due to denitrification. Denitrification was shown to be greatly influenced by the season, with a maximum rate occurring in the spring or early summer, and concurred with the period of maximum rate of plant uptake of N. Denitrifiers were capable of competing with high rates of plant uptake since the rate of denitrification was similar in fallow and cropped systems. The form of N application (NO3−, NH4+, NH4+ plus N-serve) did not significantly affect the denitrification rate. The soil used in this study fixed 34–60% of the 150 kg NH4+/ha fertilizer immediately upon application. The fixed fertilizer N was available to barley, with 71–96% of the recently fixed NH4+ being released over the growth period. The presence of N-serve resulted in less fixed fertilizer NH4+ being released during crop growth.