ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Chiral Building Units from Carbohydrates, VII1). - Synthesis of (2S)-2,3-Dihydro-2-isopropyl-2,5-dimethylfuran, the Enantiomer of the Pheromone of Hylecoetus dermestoides (L.)The synthesis of the title compound II starting from D-glucose is described. Key compound for the preparation is the methyl 2-C-acetyl-4,6-O-benzylidene-3-deoxy-α-D-ribo-hexopyranoside (I) with firm chirality at C-2.
Notes:
Es wird die Synthese der Titelverbindung II aus D-Glucose beschrieben. Schlüsselverbindung für die Darstellung ist das mit gesicherter Chiralität an C-2 eingesetzte Methyl-2-C-acetyl-4,6-O-benz-yliden-3-desoxy-α-D-ribo-hexopyranosid (I).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.198219820411
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